Preparation of Large-sized Microencapsulated Phase Change Materials Through Pickering Emulsion Stabilized by Monodisperse Polymer Microspheres

doi:10.7503/cjcu20200235

Abstract

Abstract:

Monodispersive poly(glycidyl methacrylate)(PGMA) microspheres were prepared by dispersive polymerization and then were hydrolyzed to obtain oil-in-water Pickering stablizer. Based on phase separation mechanism, microcapsulated phase change material(MePCM) with PSt and PGMA composite shell were prepared by Pickering emulsion polymerization. The MePCM was characterized by large diameter(76 μm averagely), high core content[w(dodecanol)=83%] and excellent energy storage capability(phase change enthalpy of 174 J/g).

Key words: Microencapsulated phase change material, Pickering emulsion, Polymer microsphere, Dispersion polymerization

CLC Number:

O633

TrendMD:

LI Boxin, YANG Junge, YIN Dezhong, GAO Chengqian, ZHANG Qiuyu. Preparation of Large-sized Microencapsulated Phase Change Materials Through Pickering Emulsion Stabilized by Monodisperse Polymer Microspheres[J]. Chem. J. Chinese Universities, 2020, 41(9): 2085.

Figures/Tables 9

References 25

1	Song Y. F., Lou H. F., Lv C. L., New Chem. Mater., 2018, 46(9), 30—33,40(宋云飞, 娄鸿飞, 吕绪良. 化工新型材料 , 2018, 46(9), 30—33, 40)
2	Zhang H., Li W., Huang R., New J. Chem., 2017, 41(23), 14696—14707
3	Lu J. L., Li Y., Han Y. F., Chi B. J., Qian P. P., Chinese J. Process Eng., 2019, 19(4), 661—667(鲁进利, 李洋, 韩亚芳, 池帮杰, 付钱平. 过程工程学报, 2019, 19(4), 661—667)
4	Liang F. S., Chen W. X., Ma A. J., Polym. Mater. Sci. Eng., 2018, 34(2), 150—154
5	Zhang X. P., Luo J., Jing T. F., Colloid Surfaces B Biointerfaces, 2018, 165, 165—171
6	Binks B. P., Langmuir, 2017, 33(28), 6947
7	Rodriguez A. M., Binks B. P., Curr. Opin. Colloid Interface Sci., 2019, 44, 107—129
8	Yang Y. Q., Fang Z. W., Chen X., Frontiers in Pharmacology, 2017, 8, 287—307
9	Wang X., Chen L. L., Sun G. Q., Macromol. Chem. Phys., 2019, 220, 1800395
10	Wu H., Zhang X., Zhao X., J. Membrane Sci., 2020, 595-613, 117480
11	Jiang X., Liu F., Lei Z. X., Lv Y., Liu Y. H., Jing X. L., Mater. Rev., 2017, 31(7), 94—100(姜雪, 刘锋, 雷子萱, 吕游, 刘育红, 井新利. 材料导报, 2017, 31(7), 94—100)
12	Li X. K., Zhao Y., Wang K., Chen J. L.,Song J. P., Aviation Manufacturing Technology, 2018, 61(14), 74—78, 90(李学宽, 肇研, 王凯, 陈俊林, 宋九鹏. 航空制造技术, 2018, 61(14), 74—78, 90)
13	Sun R., Gao Y. J., Shi H. B., China Optics, 2018, 11(3), 444—458(孙瑞, 高银佳, 史海斌. 中国光学, 2018, 11(3), 444—458)
14	Dan⁃Thuy V. P., Minh T. N., Ken O., Hideyuki N., Tomohisa N., Qui T. C. M., Adv. Nat. Sci: Nanosci. Nanotechnol., 2017, 8(2), 025003
15	Tang S., Zhang R., Liu F., Euro Polym. J., 2015, 72, 83—88
16	Asai S., Majumdar S., Gupta A., Kargupta K., Ganguly S., Comput. Mater. Sci., 2009, 47, 193—199
17	Salek P., Horak D., Hromadkova J., Polym. Sci. Series B, 2018, 60(1), 9—15
18	Wang T. Y., Fan H. J., Chen Y., Xu P. F., Polym. Mater. Sci. Eng., 2019, 35(2), 41—46, 53(王天佑, 范浩军, 陈意, 许平凡. 高分子材料科学与工程, 2019, 35(2), 41—46, 53)
19	Park S. H., Kim J., Lee W., Langmuir, 2017, 33(9), 2275—2282
20	Song J. S., Tronc F., Winnik M. A., J. Am. Chem. Soc., 2004, 126(21), 6562—6563
21	Liu J. J., Yin D. Z., Zhang S., Colloid Surfaces A, 2015, 466, 174—180
22	Yin D. Z., Bai L. C., Jia Y., Soft Matter, 2017, 13(20), 3720—3725
23	Cong H., Yu B., Gao L., RSC Advances, 2018, 8(5), 2593—2598
24	Yin D. Z., Ma L., Liu J. J., Zhang Q. Y., Energy, 2014, 64, 575—581
25	Yin D. Z., Jia Y., Chen J. H., Zhang B. L., J. Mater. Sci., 2018, 53, 7249—7257

Sample	V_monomer^a/mL	V_dodecanol/mL	Dimeter/μm	w_Core^b(%)	T_pm^c/℃	T_PC^d/℃	Enthopy/(J·g^-1)	w_Core^e(%)
M80	0.2	0.8	67	83	25.6	20.4	174	82.5
M70	0.3	0.7	72	72	25.5	20.2	154	73.1
M60	0.4	0.6	76	66	25.3	19.8	142	67.3

Sample	V_monomer^a/mL	V_dodecanol/mL	Dimeter/μm	w_Core^b(%)	T_pm^c/℃	T_PC^d/℃	Enthopy/(J·g^-1)	w_Core^e(%)
M80	0.2	0.8	67	83	25.6	20.4	174	82.5
M70	0.3	0.7	72	72	25.5	20.2	154	73.1
M60	0.4	0.6	76	66	25.3	19.8	142	67.3

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