Chem. J. Chinese Universities ›› 2014, Vol. 35 ›› Issue (1): 48.doi: 10.7503/cjcu20130487
• Organic Chemistry • Previous Articles Next Articles
TANG Yinmin1, HUO Yanping1,*(), HU Sheng1, ZHANG Kun1, ZHAO Fenghua1, OUYANG Xinhua2
Received:
2013-05-24
Online:
2014-01-10
Published:
2013-07-02
Contact:
HUO Yanping
E-mail:yphuo@gdut.edu.cn
CLC Number:
TrendMD:
TANG Yinmin, HUO Yanping, HU Sheng, ZHANG Kun, ZHAO Fenghua, OUYANG Xinhua. Synthesis and Photoelectricity of Novel Zn Metal Complex Based on 8-Hydroxyquinoline with Thiophene Group†[J]. Chem. J. Chinese Universities, 2014, 35(1): 48.
Compound | 3 | 4 | Z | 8 | 4 |
---|---|---|---|---|---|
Empirical formula | C17H13NO2S | C15H11NOS | rρc/(g·cm-3) | 1.338 | 1.371 |
Mr | 295.34 | 253.31 | μ/mm | 0.224 | 0.249 |
T/K | 173(2) | 173(2) | F(000) | 1232 | 528 |
Crystal system | Orthorhombic | Orthorhombic | S | 1.028 | 1.139 |
Space group | Pbca | P212121 | Reflections collected | 14825 | 5768 |
a/nm | 115.860(18) | 61.344(15) | Unique collected | 2865 | 2378 |
b/nm | 97.043(15) | 81.39(2) | Rint | 0.0216 | 0.0231 |
c/nm | 260.81(4) | 245.85(6) | 0.0358 | 0.0515 | |
V/nm3 | 2932400(8) | 1227500(5) | w | 0.1357 | 0.1593 |
Table 1 Crystallographic data for compounds 3 and 4
Compound | 3 | 4 | Z | 8 | 4 |
---|---|---|---|---|---|
Empirical formula | C17H13NO2S | C15H11NOS | rρc/(g·cm-3) | 1.338 | 1.371 |
Mr | 295.34 | 253.31 | μ/mm | 0.224 | 0.249 |
T/K | 173(2) | 173(2) | F(000) | 1232 | 528 |
Crystal system | Orthorhombic | Orthorhombic | S | 1.028 | 1.139 |
Space group | Pbca | P212121 | Reflections collected | 14825 | 5768 |
a/nm | 115.860(18) | 61.344(15) | Unique collected | 2865 | 2378 |
b/nm | 97.043(15) | 81.39(2) | Rint | 0.0216 | 0.0231 |
c/nm | 260.81(4) | 245.85(6) | 0.0358 | 0.0515 | |
V/nm3 | 2932400(8) | 1227500(5) | w | 0.1357 | 0.1593 |
D-H…A | D-H/nm | H…A/nm | D…A/nm | ∠D-H…A/(°) |
---|---|---|---|---|
O1-H1…N1 | 0.085 | 0.218 | 0.26521 | 115 |
C11-H11A…N1 | 0.095 | 0.250 | 0.28423 | 101 |
Table 2 Hydrogen bond lengths and bond angles of compound 4
D-H…A | D-H/nm | H…A/nm | D…A/nm | ∠D-H…A/(°) |
---|---|---|---|---|
O1-H1…N1 | 0.085 | 0.218 | 0.26521 | 115 |
C11-H11A…N1 | 0.095 | 0.250 | 0.28423 | 101 |
Device | Luminance/(cd·m-2) | Voltage of turn-on/V | Efficiency/(cd·A-1) |
---|---|---|---|
A | 980 | 5.2 | 0.84 |
B | 420 | 8.6 | 0.22 |
C | 540 | 8.2 | 0.36 |
Table 3 Electroluminescent parameters of complex 5 in different device structures
Device | Luminance/(cd·m-2) | Voltage of turn-on/V | Efficiency/(cd·A-1) |
---|---|---|---|
A | 980 | 5.2 | 0.84 |
B | 420 | 8.6 | 0.22 |
C | 540 | 8.2 | 0.36 |
[1] | Zeng H. P., Wang G. R., Zeng G. C., Li J., Dyes and Pigments, 2009, 83, 155-161 |
[2] | Wang G. R., Li X. C., Zeng H. P., Acta Chim. Sinica, 2009, 67(9), 974-982 |
(王光荣, 李熙灿, 曾和平.化学学报, 2009,67(9), 974-982) | |
[3] | Ding G. Y., Wang L. Z., Han Q., Chang X., Journal of Optoectronics·Laser, 2011, 22(1), 60-63 |
(丁桂英, 王立忠, 韩强, 常喜.电子·激光, 2011,22(1), 60-63) | |
[4] | Ouyang X. H., Wang G. R., Zeng H. P., Zhang W. M., Li J., J. Organomet. Chem., 2009, 694, 3511-3517 |
[5] | Wang T. T., Zeng G. C., Zeng H. P., Liu P. Y., Wang R. X., Zhang Z. J., Xiong Y. L., Tetrahedron, 2009, 65, 6325-6329 |
[6] | Sharma A., Singh D., Makrandi J. K., Makrandi J. K., Kamalasanan M. N., Shrivastva R., Singh I., Mater. Lett., 2007, 61, 4614-4617 |
[7] | Yuan G. Z., Huo Y. P., Nie X. L., Fang X. M., Tetrahedron, 2012, 68, 8018-8023 |
[8] | Spiekermann S., Smestad G., Kowalik J., Kowalik J., Tolbert L. M., Grätzel M., Synth. Met., 2001, 121, 1603-1604 |
[9] | Du N. Y., Mei Q. B., Lv M. G., Acta Chim. Sinica, 2004, 35, 238-246 |
(杜乃婴, 梅群波, 吕满庚.化学学报, 2004, 35, 238-246) | |
[10] | Wang W., Ma J. H., Dong F., Hao Y. Z., Chemical Research and Application, 2007, 19(2), 207-209 |
(王伟, 马建华, 董芳, 郝彦忠.化学研究与应用, 2007,19(2), 207-209) | |
[11] | Xiao T.M., Research on the Synthesis and Optical Properties of Poly(3-phenylthiophene), Inner Mongolia University for the Nationalities,Tongliao, 2006 |
(肖田梅. 聚3-苯基噻吩的合成及其光学性能研究, 通辽: 内蒙古民族大学, 2006) | |
[12] | Lu W. T., Yang J. P., Acta Chim. Sinica, 2013, 71, 121-125. |
(卢伟涛, 杨继萍.化学学报, 2013, 71, 121-125) | |
[13] | Luisa R., Licinia L. G. J., Adriana B., Sofia M. F., Hugh D. B., Polyhedron, 2013, 52, 743-749 |
[14] | Jin H. K., Jin Y. N., In H. H., Juhye K., Jin H. K., Cheal K., Tetrahedron Letters, 2013, 54, 2415-2418 |
[15] | Evandro S., Tiago A. S. B., Haidi D. F., Faruk N., J. Colloid Interf. Sci., 2007, 314, 214-222 |
[16] | Tong B. H., Mei Q. B., Li Z. W., Acta Chim. Sinica, 2012, 70, 2451-2456 |
(童碧海, 梅群波, 李志文.化学学报, 2012, 70, 2451-2456) | |
[17] | Xie X., Jiang X. J., Liu J., Ren X. Y., Wang H. M., Liu X. M., Inorg. Chim. Acta, 2012, 383, 132-136 |
[18] | Zhao A. T., Xiong Y. L., Zeng H. P., Chem. J. Chinese Universities, 2011, 32(5), 1094-1099 |
(赵爱婷, 熊艳玲, 曾和平.高等学校化学学报, 2011,32(5), 1094-1099) | |
[19] | Duraisamy U., Sivan V., J. Luminescence, 2013, 136, 117-121 |
[20] | Yan G. Z., Huo Y. P., Nie X. L., Jiang B., Liu B., Fang X. M., Zhao F. H., Dalton Transactions, 2013, 42, 2921-2929 |
[21] | Huo Y. P., Dai L. L., Huang B. H., Zhang K., Fang Y. X., Liu J., Chin. J. Org. Chem., 2012, 32, 538-543 |
(霍延平, 戴立立, 黄宝华, 张焜, 方岩雄, 刘军.有机化学, 2012, 32, 538-543) |
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