Catalytic Performance of the Ni/ZrO2 Catalysts Prepared with the Hydrogel Method in Methanation of CO2

doi:10.7503/cjcu20130285

Abstract

Abstract:

A series of Ni/ZrO₂ catalysts was prepared by the hydrogel method and characterized by X-ray diffraction(XRD), Brunauer-Emmett-Tetter(BET), transmission electron microscopy(TEM) and H₂ temperature programmed reduction(H₂-TPR), and their catalytic activities for the methanation of carbon dioxide were investigated. The results show that ZrO₂ presents an amorphous structure in the Ni/ZrO₂ catalysts after calcination at 450℃. During the H₂ reduction at the temperature of 400 ℃, the amorphous ZrO₂ carrier was partly transformed into tetragonal phase and Ni species were re-dispersed on the surface of ZrO₂. The metal-support interaction restrains the growth of NiO and ZrO₂, and electron cavity on amorphous ZrO₂ carrier favors the dispersion of Ni species. The NiO species interacted with amorphous ZrO₂ and tetragonal ZrO₂ has a definitive effect on the catalytic performance of the Ni/ZrO₂ catalysts. The highest catalytic activity was obtained on the Ni/ZrO₂ catalyst with a Ni/Zr molar ration of 0.707. Under the reaction condition, V(CO₂)/V(H₂)=1/4, gaseous hourly space velocity(GHSV)=1×10⁴ h^-1, P=0.5 MPa, 27% CO₂ conversion was obtained at a low temperature of 200 ℃. The conversion of CO₂ reached above 99% with the selectivity of CH₄ above 92% when the reaction temperature was improved to 280—320 ℃.

Key words: Ni/ZrO₂ catalyst, CO₂, Methanation, Hydrogel method

CLC Number:

O643.3

TrendMD:

LIU Quan, REN Jun, QIN Zhi-Feng, MIAO Mao-Qian, LI Zhong. Catalytic Performance of the Ni/ZrO₂ Catalysts Prepared with the Hydrogel Method in Methanation of CO₂[J]. Chem. J. Chinese Universities, 2013, 34(9): 2171.

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Catalytic Performance of the Ni/ZrO₂ Catalysts Prepared with the Hydrogel Method in Methanation of CO₂

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