Synthesis and Characterization of a Novel Mixed-valence Vanadogermanate Cluster [Ge6V6VV9ⅣO42(OH)6(H2O)]

doi:10.3969/j.issn.0251-0790.2012.08.003

Abstract

Abstract: A novel mixed-valence vanadogermanate cluster [Ge₆V₆^VV₉^ⅣO₄₂(OH)₆(H₂O)]·6(1,6-DAH)·21H₂O(1)(1,6-DAH: 1,6-diamimohexane) was hydrothermally synthesized and characterized by elemental analysis, IR, XPS and so on. Single crystal X-ray diffraction shows that compound 1 exhibits a heart-like shape derived from the spherical {V₁₈O₄₂} archetype. The magnetic study shows that there exists weak anterferromagnetic interaction within the cluster.

Key words: Hydrothermal synthesis, Mixed-valence, Vanadogermanate cluster, Magnetic property

CLC Number:

O614

TrendMD:

WANG Lei, WANG Yan-Yan, LI Yi, LIANG Zhi-Qiang. Synthesis and Characterization of a Novel Mixed-valence Vanadogermanate Cluster [Ge₆V₆^VV₉^ⅣO₄₂(OH)₆(H₂O)][J]. Chem. J. Chinese Universities, 2012, 33(08): 1646.

References

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Synthesis and Characterization of a Novel Mixed-valence Vanadogermanate Cluster [Ge₆V₆^VV₉^ⅣO₄₂(OH)₆(H₂O)]

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