Strong Two-photon Absorption and Electrochemical Behavior of Dibenzofuran-triphenylamine Dentritic Chromophores

Chem. J. Chinese Universities

• 研究论文 • Previous Articles Next Articles

Strong Two-photon Absorption and Electrochemical Behavior of Dibenzofuran-triphenylamine Dentritic Chromophores

ZHANG Wei-Zhou¹, WANG Xiao-Mei¹*, FANG Xiang-Yun², JIANG Wan-Li³, ZHAO Jun-Fang²

1. Institute of Material Science and Engineering, Suzhou University, Suzhou 215021, China;
2. Laboratory of Ultra-Fast Laser, Measurement and Test Center, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, China;
3. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

Received:2007-12-12 Revised:1900-01-01 Online:2008-08-10 Published:2008-08-10
Contact: WANG Xiao-Mei

Abstract

Abstract: The motivation for the strong two-photon absorbing chromophore is based on the significantly potential applications such as three-dimensional fluorescence imaging, two-photon photodynamic therapy, optical data storage and TPE fluorescence microscopy. Thus, the relationship between molecular structure and strong TPA property is greatly valuable. Here, two-photon absorption(TPA) and electro-chemistry properties of three new dibenzofuran-based chromophores(named as OT-G1, OT-G1.5 and OT-G2) were investigated. Stronger two-photon fluorescence(TPF) and larger TPA cross-section were observed with the generation number increasing. It is interesting to find that the increasing of the HOMO energy level shows the contribution to enhancement of TPA cross-section.

Key words: Dibenzofuran-triphenylamine dentritic chromophore, Two-photon absorption, Two-photon fluorescence, HOMO energy level

CLC Number:

O644.1

TrendMD:

ZHANG Wei-Zhou¹, WANG Xiao-Mei¹*, FANG Xiang-Yun², JIANG Wan-Li³, ZHAO Jun-Fang². Strong Two-photon Absorption and Electrochemical Behavior of Dibenzofuran-triphenylamine Dentritic Chromophores[J]. Chem. J. Chinese Universities, doi: .

[1]	LIU Miao, LIU Ruibo, LIU Badi, QIAN Ying. Synthesis， Two-photon Fluorescence Imaging and Photodynamic Therapy of Lysosome-targeted Indole-BODIPY Photosensitizer [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220326.
[2]	HUANG Chibao, PAN Qi, CHEN Huashi, LIANG Xing, LÜ Guoling. Triphenylamine-based Dicyanostilbene Type Two-photon Fluorescence Solvatochromic Probe^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1676.
[3]	HUANG Chibao,PAN Qi,CHEN Huashi,LIANG Xing,LÜ Guoling. Dicyanostilbene-derived Two-photon Fluorescence Probe for Lead Ions^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 897.
[4]	HUANG Chibao, PAN Qi, CHEN Xiaoyuan, ZHAO Guanglian, CHEN Huashi, LIANG Xing, LÜ Guoling. Dicyanostilbene-derived Two-photon Fluorescence Probe for Mercury Ions^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1751.
[5]	HUANG Chibao, LIANG Xing, ZENG Qihua, CHEN Huashi, ZENG Boping, YI Daosheng, CHEN Xiaoyuan. Dicyanostilbene-derived Two-photon Fluorescence Probe for Free Zinc Ions in Live Cells and Living Tissues^† [J]. Chem. J. Chinese Universities, 2015, 36(4): 646.
[6]	GAO Yuanhao, PAN Ruilong, TIAN Yupeng, LI Jing, ZHENG Zhi. Syntheses and Optical Properties of Two Novel Terpyridine Derivatives^† [J]. Chem. J. Chinese Universities, 2014, 35(7): 1439.
[7]	QIAN Ying*, LIN Guo-Qiang, ZHOU Zhi-Qiang, CUI Yi-Ping. Two-photon Upconversion Fluorescence Property in a Star-shaped Pyridine Chromophore [J]. Chem. J. Chinese Universities, 2011, 32(4): 868.
[8]	QIAN Ying*, Lü Xin-Ming, ZHOU Zhi-Qiang, CUI Yi-Ping. Multiphoton Pumped Green Fluorescence in a Hyperbranched Triphenylamine-oxadiazole Conjugated Polymer [J]. Chem. J. Chinese Universities, 2011, 32(10): 2441.
[9]	JIA Peng-Fei, LIU Heng, ZHANG Yuan-Hong, LIU Xin, ZHAO Ning, YU Xiao-Qiang. Novel Two-photon Fluorescent Probe 2,7-BHVC for DNA Imaging [J]. Chem. J. Chinese Universities, 2010, 31(6): 1075.
[10]	XU Hong, YANG Shu-Min, CHEN Geng, TIAN Lei-Lei, HE Feng, WANG Guang-Yi, .... Organic Two-photon Fluorescence Nanoparticles for Cell Stains [J]. Chem. J. Chinese Universities, 2010, 31(4): 632.
[11]	HUANG Chi-Bao, REN An-Xiang, LI Hai-Bo, YANG Nian-Fa* . Synthesis of Bis(styryl)benzene Derivatives of Typical A-A-A Conjugation Structure with Large Two-photon Absorption Cross Sections [J]. Chem. J. Chinese Universities, 2010, 31(11): 2222.
[12]	LI Wen-Chao1, FENG Ji-Kang1,2*, REN Ai-Min1, SUN Chia-Chung1, YU Xiao-Qiang3, WA. Theoretical Studies for One- and Two-photon Absorption Properties of 3,6- and 2,7-Carbazole Derivatives [J]. Chem. J. Chinese Universities, 2010, 31(1): 100.
[13]	YANG Zhao-Di, FENG Ji-Kang*, REN Ai-Min. Theoretical Study of One- and Two-photon Absorption Properties for Two Series of Star-burst-typed Pseudo Octupolar Molecules [J]. Chem. J. Chinese Universities, 2009, 30(7): 1417.
[14]	TAN Hai-Rong, ZENG He-Ping*. Electrochemistry Behavior and Two-photon Absorption Characteristic of C₆₀/C₇₀ Bonded with 1,4-Bis[(carbazole-9-yl)methyl]benzene [J]. Chem. J. Chinese Universities, 2009, 30(5): 934.
[15]	LIU Xin¹, LIU Heng^1, JIA Peng-Fei¹, ZHANG Bo¹, WANG Jun-Jie², ZHAO Ning², ZHANG Yuan-Hong², YU Xiao-Qiang^2. New Two-photon Fluorescence Probe for Nuclear DNA Imaging [J]. Chem. J. Chinese Universities, 2009, 30(3): 465.

Strong Two-photon Absorption and Electrochemical Behavior of Dibenzofuran-triphenylamine Dentritic Chromophores

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments