Synthesis, Crystal Structure and Characterization of Carboxylic Derivatives of Sulfonylcalix[4]arene

Chem. J. Chinese Universities

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Synthesis, Crystal Structure and Characterization of Carboxylic Derivatives of Sulfonylcalix[4]arene

GUO Qian-Ling¹, QU Yi-Xin¹, MA Shu-Lan², ZHU Wen-Xiang²

1. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2. Department of Chemistry, Beijing Normal University, Beijing 100875, China

Received:2005-12-29 Revised:1900-01-01 Online:2006-11-10 Published:2006-11-10
Contact: QU Yi-Xin

Abstract

Abstract: The lower-rim partially substituted sulfonylcalix[4]arenes, 5,11,17,23-tetra-tert-butyl-25,26,27-tris[(ethoxycarbonyl)methoxy]-2,8,14,20-tetrasulfonylcalix[4] arene(L1) and 5,11,17,23-tetra-tert-butyl-25,26,27-tris(oxyacetic acid)-2,8,14,20-tetrasulfonyl calix[4]arene(L2), and the complexes of L2 were synthesized and characterized. The crystal structure of L1 was determined by X-ray diffraction. The results show that the composition of it is C₅₂H₆₅KO₁₈S₄·0.5H₂O. It belongs to triclinic crystal system, P1 space group, with a=1.2607(6) nm, b=1.5820(8) nm, c=1.648 0(8) nm, α=83.720(8)°, β=69.327(8)°, γ=79.342(9)°, Z=2, V=3.019(3) nm³, D_c=1.270 g·cm^-3, F(000)=121.8, μ=0.293 mm^-1, R₁=0.0937, wR₂=0.2580. The calix[4]arene adopts a partial cone conformation.

Key words: Sulfonylcalix[4]arene, Carboxylic derivative, Rare earth complex, Crystal structure

CLC Number:

O611

TrendMD:

GUO Qian-Ling¹, QU Yi-Xin¹, MA Shu-Lan², ZHU Wen-Xiang². Synthesis, Crystal Structure and Characterization of Carboxylic Derivatives of Sulfonylcalix[4]arene
[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Crystal Structure and Characterization of Carboxylic Derivatives of Sulfonylcalix[4]arene

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