Synthesis and Crystal Structure of a Three-dimensional Supramolecular Network [Cu2(ETU)6]SO4 Based on Hydrogen Bonds

Chem. J. Chinese Universities

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Synthesis and Crystal Structure of a Three-dimensional Supramolecular Network [Cu₂(ETU)₆]SO₄ Based on Hydrogen Bonds

ZHANG Jing, ZHU Qin-Lei, HUANG Ru-Dan, FU Yin-Xia, HU Chang-Wen

Department of Chemistry, School of Science, Beijing Institute of Technology, Beij
ing 100081, China

Received:2006-04-30 Revised:1900-01-01 Online:2006-11-10 Published:2006-11-10
Contact: HU Chang-Wen

Abstract

Abstract: A novel coordination polymers [Cu₂(ETU)₆]SO₄(1)(ETU=ethylidene thiourea) was synthesized under solvothermal conditions. The crystal structure of the polymer was determined by X-ray diffraction: trigonal, space group R3c(No. 161), a=1.27509(8) nm, b=1.27509(8) nm, c=3.5747(7) nm, γ=120°, Z＝6, CCDC Number: 605501. In the structure of the polymer, each metal ion Cu(Ⅰ) coordinates to three S atoms attached to the ring of ETU forming two triangular pinwheel-shape monovalent cations [Cu(ETU)₃]⁺, in one of which the counter-ion SO^2-₄ is located. The ions with contrary charge, [Cu(ETU)₃]⁺ and SO^2-₄, are held together via the N—H…O hydrogen-bonded interactions resulting in a three-dimensional supramolecular network.

Key words: Solvothermal synthesis, Supramolecular network, Hydrogen-bond, Ethylidene thiourea

CLC Number:

O614

TrendMD:

ZHANG Jing, ZHU Qin-Lei, HUANG Ru-Dan, FU Yin-Xia, HU Chang-Wen. Synthesis and Crystal Structure of a Three-dimensional Supramolecular Network [Cu₂(ETU)₆]SO₄ Based on Hydrogen Bonds[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Crystal Structure of a Three-dimensional Supramolecular Network [Cu₂(ETU)₆]SO₄ Based on Hydrogen Bonds

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