Chem. J. Chinese Universities

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Preparation and Electrical Properties of Composite Cathode Material La1-xSrxCuO3-δ-SDC for IT-SOFCs

ZHENG Min-Zhang1, LIU Xiao-Mei1, ZHU Cheng-Jun1, XU Dan1, SUN Jing-Shu1, SU Wen-Hui1,2
  

    1. Department of Physics,
    2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:2005-12-05 Revised:1900-01-01 Online:2006-11-10 Published:2006-11-10

Abstract: The cathode material La1-xSrxCuO3-δ(x=0.15, 0.2, 0.3, 0.4) was synthesized by a sol-gel method. X-ray diffraction reveals that it is a single phase of perovskite. The investigation of the electrical properties suggest that La0.7Sr0.3CuO3-δ has the highest electrical conductivity. La0.7Sr0.3CuO3-δ powder was mixed with different amount of SDC(Sm0.15Ce0.85O1.925) powder(5%—30%, mass fraction) as composite cathodes. Electrochemical properties of the composite cathodes were researched further. The investigation suggests the addition of appropriate amount SDC to La0.7Sr0.3CuO3-δ can improve the electrochemical properties, and a better cathodic performance can be obtained. Using La0.7Sr0.3CuO3-δ-SDC composite materials as a cathode based on SDC electrolyte higher current density and power density can be obtained at intermediate temperatures.

Key words: IT-SOFC, Composite cathode, La1-xSrxCuO3-δ, SDC

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