Study of Caged Bicyclic Phosphates (Ⅱ)——Synthesis of Derivatives of 1-Sulfo-1-Phospha-4-Methylene-2,6,7-Trioxabicyclo[2,2,2]octane

Chem. J. Chinese Universities ›› 1989, Vol. 10 ›› Issue (10): 1002.

• Articles • Previous Articles Next Articles

Study of Caged Bicyclic Phosphates (Ⅱ)——Synthesis of Derivatives of 1-Sulfo-1-Phospha-4-Methylene-2,6,7-Trioxabicyclo[2,2,2]octane

Li Yugui¹, Wang Jianji¹, Liu Yunshan¹, Han Jiaxiang¹, Cao Jinhong², Jiang Xiaochun²

1. Institute of Elemento-Organic Chemistry, Nankai University, Tianjin;
2. Academy of Military Medical Science, Beijing

Received:1988-05-05 Online:1989-10-24 Published:1989-10-24

Abstract

Abstract: Eleven new compounds with the formula 3 were synthesized by phosphonothiolation reaction of bicyclic phosphate 1 with phosphonothioyl chloide 2 in the presence of DMAP(4-N,N-dimethy-laminopyridine) and Et₃N.The outstanding catalysis of DMAPis studied.The structure of compound 3 was confirmed by elemental analysis, IR, ¹H NMRand MS.It has been shown that some of these compounds have activities of plant growth regulator by the priliminary biological tests.

Key words: Caged bicyclic phosphate, Phosphonate, DMAP, Phosphorylation, Heterocyclic compound

TrendMD:

Li Yugui, Wang Jianji, Liu Yunshan, Han Jiaxiang, Cao Jinhong, Jiang Xiaochun. Study of Caged Bicyclic Phosphates (Ⅱ)——Synthesis of Derivatives of 1-Sulfo-1-Phospha-4-Methylene-2,6,7-Trioxabicyclo[2,2,2]octane[J]. Chem. J. Chinese Universities, 1989, 10(10): 1002.

[1]	YOU Yipeng, NIE Lin, LIU Jinbiao, FENG Yahui, LU Gui. Design， Synthesis and Anti-influenza Activities of Novel Neuraminidase Inhibitors^† [J]. Chem. J. Chinese Universities, 2020, 41(10): 2279.
[2]	ZOU Xiaochuan,WANG Yue,WANG Cun,HU Shiwen,SHI Kaiyun. Synthesis of Amine Functionalized ZPS-PVPA Supported Chiral Mn^Ⅲ(salen) and Asymmetric Catalytic Olefin Epoxidation^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1488.
[3]	LI Qintao, SUN Wen, ZHANG Qin, PAN Huifen, XU Jie. In Situ Crystallized Zirconium Phenylphosphonate Films on the Copper Mesh and Its Application in Oil/water Separation^† [J]. Chem. J. Chinese Universities, 2017, 38(3): 464.
[4]	GUO Zhenghong, FANG Zhengping, CHEN Chao. Synergistic Flame Retardant and Suppression Smoke Mechanism of Cerium Phenylphosphonate and Decabromodiphenyl Oxide in Glass-fiber Reinforced Poly(1,4-butylene terephthalate) Composites^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 284.
[5]	XIONG Zhen, JI Siping, CHUAN Yongming, JIANG Lin, YUAN Minglong. Synthesis Method of β-Aminophosphonate Derivatives^† [J]. Chem. J. Chinese Universities, 2015, 36(6): 1112.
[6]	ZHAO Chaoyue, WANG Na, WANG Juanjing, HE Xi, LI Jiang. Construction and Functional Detection of Mutant Plasmid EMMPRIN Phosphorylation^† [J]. Chem. J. Chinese Universities, 2014, 35(10): 2104.
[7]	FA Huan-Bao, ZHANG Jin, QI Hui, YIN Wei, ZHANG Hai-Feng, HOU Chang-Jun, HUO Dan-Qun, LU Wei-Jian. Synthesis and Properties of Molecularly Imprinted Polymeric Microspheres of Metalloporphyrins with Dimethyl Methylphosphonate as Template Molecule [J]. Chem. J. Chinese Universities, 2013, 34(5): 1160.
[8]	ZOU Xiao-Chuan, SHI Kai-Yun, CHEN Shao-Cheng, FU Xiang-Kai. Synthesis of Hybrid Supports ZPS-IPPA and Application for Heterogeneous Olefin Epoxidation [J]. Chem. J. Chinese Universities, 2013, 34(10): 2319.
[9]	MIAO Qiang, FU Xiang-Kai, HUANG Jing, LI Chao, CHEN Guo-Dong, WANG Guo-Ming. Synthesis and Characterization of Novel Layered Crystalline Organic Polymer-inorganic Hybrid Materials Zinc Poly(styrene-phenylvinyl phosphonate)-phosphate Ammonium [J]. Chem. J. Chinese Universities, 2012, 33(09): 1984.
[10]	ZHANG Bian-Xiang, YANG Qi, HE Xiao-Xia, CHAO Jian-Bin, CHANG Jiao, WU Qun. Synthesis and Characterization of a Series of Olefinated Aromatic Heterocyclic Compounds [J]. Chem. J. Chinese Universities, 2012, 33(07): 1471.
[11]	CHEN Liang-Bing, DU Li-Bo, TIAN Qiu, JIA Hong-Ying, GAO Yan-Li, LIU Yang. Effect of Phosphorylation on the Production of 7900 and 9300 Fragments of D1 Protein [J]. Chem. J. Chinese Universities, 2012, 33(07): 1493.
[12]	ZHAO Jing, XU Hong-Jie, FANG Jian-Hua, YIN Jie. Synthesis and Characterization of Sulfonated Polyamides [J]. Chem. J. Chinese Universities, 2012, 33(05): 1106.
[13]	HU Xiao-Yan, FU Xiang-Kai*, LIU Zhi-Jian, XU Jiang-Wei, LUO Yun-Fei. Synthesis of Chiral Salen Mn(Ⅲ) Immobilized on Novel Layered Crysalline Hybrid Support Zinc Poly(styrene-phenylvinylphosphonate)-phosphate as Effective Catalysts and Asymmetric Epoxidation of Unfuntionalized Olefins [J]. Chem. J. Chinese Universities, 2011, 32(11): 2605.
[14]	LI Hua*, REN Ha, ZHANG Wei-Wei, QIU Shi-Lun, ZHU Guang-Shan. Synthesis, Structure and Gas Adsorption Property of a Novel 2D Layer Nickel Organo-diphosphonate Compound [J]. Chem. J. Chinese Universities, 2011, 32(1): 28.
[15]	NIU Xiao-Di, LIU Jing-Bo, WANG Song, WANG Hong-Su, NIAN Gui-Jun. Efficient Polymer Red Light-emitting Diodes with Cathode Interface Modification Layer Based on Phosphonate Polyfluorene [J]. Chem. J. Chinese Universities, 2010, 31(9): 1874.

Study of Caged Bicyclic Phosphates (Ⅱ)——Synthesis of Derivatives of 1-Sulfo-1-Phospha-4-Methylene-2,6,7-Trioxabicyclo[2,2,2]octane

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments