Chem. J. Chinese Universities ›› 1992, Vol. 13 ›› Issue (6): 774.

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Synthesis of Substituted Phenyl Perfluoroalkyl Ketones

GONG Yue-fa, MA Yan-long, QU Yan-ling, ZHAO Cheng-xue   

  1. Department of Chemistry, Iluazhong University of Science and Technology, Wuhan, 430074
  • Received:1991-07-19 Online:1992-06-24 Published:1992-06-24

Abstract: By the reactions between substituted phenylmagnesium halides and perfluorocarboxylic acids in tetrahydrofuran, nine substituted phenyl perfluoroalkyl ketones (1~9) were synthesized and characterized by IR, UV, 1H NMR, 19F NMR and MS.The ketones 6, 7, 8 and 9 are new and useful fluorinated compounds.

Key words: Perfluoroalkylaryl ketones, Substituted phenyl magnesium halides, Perfluorocarboxylic acids, EPR

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