Preparation and Characterization of Two GdCl3-galactitol Complexes

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (6): 1244.

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Preparation and Characterization of Two GdCl3-galactitol Complexes

YU Lei¹, HUA Xiao-Hui², ZHAI Yan-Jun^1*, YANG Li-Min^3*, ZHAO Guo-Zhong⁴, MENG Tian-Hua⁴, WENG Shi-Fu², XU Yi-Zhuang², LIU Ke-Xin³, WU Jin-Guang², CHEN Jia-Er³

1. College of Pharmacy, Liaoning University of Traditional Chinese Medicine, Dalian 116600, China;
2. College of Chemistry and Molecular Engineering,
3. State Key Laboratory of Nuclear Physics and Technology, Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871, China;
4. Department of Physics, Capital Normal University, Beijing 100037, China

Received:2010-09-13 Revised:2010-11-26 Online:2011-06-10 Published:2011-05-10
Contact: ZHAI Yan-Jun;YANG Li-Min E-mail:lnzyzyj@sohu.com;yanglm@pku.edu.cn
Supported by:
国家“九七三”计划项目(批准号: 2002CB713600)和国家自然科学基金(批准号: 21001009, 50973003)资助.

Abstract

Abstract: Coordination of hydroxyl groups to metal ions is common in biosystems. Here two GdCl3-galactitol complexes have been prepared, one is 2GdCl3?C6H14O6?14H2O, in which Gd3+ is coordinated to three hydroxyl groups of galactitol and six water molecules, other water molecules are hydrogen-bonded and chloride ions do not coordinate to metal ions. It is possible that Gd3+ is 9-coordinated to six hydroxyl groups from two galactitol molecules and three water molecules, the ratio of metal to galactitol is 1:1 and maybe several water molecules are hydrogen-bonded in the second GdCl3-galactitol complex according to IR, elemental analysis, FIR, THz and TGA results. The experimental results indicate that two lanthanide-galactitol complexes can be obtained, which demonstrate the complexity of the interactions between metal ions and hydroxyl groups.

Key words: galactitol, GdCl3-complex, crystal structure, far-IR spectrum, THz spectrum

CLC Number:

O 614. 33

TrendMD:

YU Lei, HUA Xiao-Hui, ZHAI Yan-Jun*, YANG Li-Min*, ZHAO Guo-Zhong, MENG Tian-Hua, WENG Shi-Fu, XU Yi-Zhuang, LIU Ke-Xin, WU Jin-Guang, CHEN Jia-Er. Preparation and Characterization of Two GdCl3-galactitol Complexes[J]. Chem. J. Chinese Universities, 2011, 32(6): 1244.

References

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Preparation and Characterization of Two GdCl3-galactitol Complexes

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