Synthesis of Organosilyl-substituted Aluminophosphate Molecular Sieves VPI-5

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (10): 2246.

• Preface • Previous Articles Next Articles

Synthesis of Organosilyl-substituted Aluminophosphate Molecular Sieves VPI-5

LIU Zhi, LI Yang-Xue, LIU Yun-Ling, HUO Qi-Sheng*

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China

Received:2011-02-25 Revised:2011-03-15 Online:2011-10-10 Published:2011-09-11
Contact: HUO Qi-Sheng E-mail:huoqisheng@gmail.com
Supported by:
国家自然科学基金(批准号：20788101, 21071059)资助.

Abstract

Abstract: Using 1,2-bis(triethoxysilyl)ethane(BTESE), 1,2-bis(triethoxysilyl)ethylene(BTESEE), and phenyltriethoxysilane(PTES) as silicon sources, organosilica functionalized Si-VPI-5 molecular sieves were synthesized under hydrothermal conditions and the effects of reaction conditions were investigated. Structural characterizations show that the Si atoms with organic groups are introduced into the molecular sieve frameworks. The introduction of organic groups increases the hydrophobicity of the molecular sieves, and the introduction of different organic groups leads to different increase degrees of the hydrophobicity on the molecular sieves.

Key words: Molecular sieve; , Organosilyl, Hydrothermal synthesis, VPI-5 molecular sieve, Lipophilicity

CLC Number:

TrendMD:

LIU Zhi, LI Yang-Xue, LIU Yun-Ling, HUO Qi-Sheng*. Synthesis of Organosilyl-substituted Aluminophosphate Molecular Sieves VPI-5[J]. Chem. J. Chinese Universities, 2011, 32(10): 2246.

[1]	LIANG Yu, LIU Huan, GONG Lige, WANG Chunxiao, WANG Chunmei, YU Kai, ZHOU Baibin. Synthesis and Supercapacitor Properties of Biimidazole-modified ｛SiW₁₂O₄₀｝ Hybrid [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210556.
[2]	ZHANG Huishuang, GAO Yanxiao, WANG Qiuxian, LI Xiangnan, LIU Wenfeng, YANG Shuting. High-low Temperature Properties of Ni-rich LiNi_0.6Co_0.2Mn_0.2O₂ Cathode Material by Hydrothermal Synthesis with CTAB Assisted [J]. Chem. J. Chinese Universities, 2021, 42(3): 819.
[3]	WANG Ye, ZHANG Xiaosi, SUN Lijing, LI Bing, LIU Lin, YANG Miao, TIAN Peng, LIU Zhongyi, LIU Zhongmin. Morphology Control of SAPO Molecular Sieves under the Assistance of Organosilane [J]. Chem. J. Chinese Universities, 2021, 42(3): 683.
[4]	WANG Jianyu, ZHANG Qiang, YAN Wenfu, YU Jihong. Roles of Hydroxyl Radicals in Zeolite Synthesis [J]. Chem. J. Chinese Universities, 2021, 42(1): 11.
[5]	WU Qinming, WANG Yeqing, MENG Xiangju, XIAO Fengshou. Reconsideration of Crystallization Process for Aluminosilicate Zeolites [J]. Chem. J. Chinese Universities, 2021, 42(1): 21.
[6]	LIU Yabing,LI Mingyang,TIAN Ge,ALATENG Shaga,PEI Tonghe,NIE Jingsi. Syntheses, Structures and Catalytic Properties of Two Supramolecular Complexes Based on 2-Pyridylamine and Cluster ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 995.
[7]	ZHUO Mengning,LI Fei,JIANG Hao,CHEN Qianwen,LI Peng,WANG Lizhang. Preparation of SnO₂/GDE Cathodes and Their Electrocatalytic Reduction of CO₂ to Produce Formic Acid ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 530.
[8]	DONG Le, HUANG Xingliang, REN Junjie, DAI Xiaoping, LIU Zongyan, TIAN Hongfeng, WANG Zhidong, WU Xiaotong. Influence Mechanism of Particle Size and Distribution of Silica Sol in the Synthesis of Ferrierite Zeolite with High SiO₂/Al₂O₃ Ratio [J]. Chem. J. Chinese Universities, 2020, 41(11): 2449.
[9]	ZHOU Hai, CHEN Hao, GUO Ya, KANG Min. Synthesis of Meso-porous Co₃O₄ Polyhedra and Their Electrochemical Properties^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1374.
[10]	GAO Ningxiao,XU Yulong,LIU Yong. Preparation of Carbon Dots from Soy Milk Powder and Fluorescent Nanofibers Containing Carbon Dots^† [J]. Chem. J. Chinese Universities, 2019, 40(3): 555.
[11]	XIA Kun, ZHOU Dan, YANG Yun, YANG Shuijin, XIA Qinghua. Efficient Synthesis of Highly Uniform AlPO₄-11 Microcrystalline and Study on the Crystallization Process^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1624.
[12]	SONG Wei, WANG Liqun, ZENG Shuangli, WANG Li, FAN Yong, XU Jianing. In situ Hydrothermal Synthesis, Crystal Structure and Fluorescence Properties of Two Cadmium Coordination Polymers^† [J]. Chem. J. Chinese Universities, 2018, 39(7): 1406.
[13]	XIA Kun,WANG Yi,ZHOU Dan,HUANG Zhe,WU Zhonghan,XIA Qinghua. Rapid Synthesis of CoSAPO-5 Zeolite and Efficiently Catalytic Epoxidation of α-Pinene with Air^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 941.
[14]	HUA Chenghe, MA Hongchao, DONG Xiaoli, ZHANG Xiufang. Synthesis and Photocatalytic Activity of α-Bi₂O₃Nanotubes/Nitrogen Doped Carbon Quantum Dots Hybrid Material^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 200.
[15]	FENG Huijie, ZHENG Wenjun. Synthesis of MoS₂ Hierarchical Nanostructure and Its Performance for Lithium-ion Battery^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1134.

Synthesis of Organosilyl-substituted Aluminophosphate Molecular Sieves VPI-5

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments