Synthesis, Structure and Gas Adsorption Property of a Novel 2D Layer Nickel Organo-diphosphonate Compound

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (1): 28.

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Synthesis, Structure and Gas Adsorption Property of a Novel 2D Layer Nickel Organo-diphosphonate Compound

LI Hua^1,2*, REN Ha², ZHANG Wei-Wei², QIU Shi-Lun², ZHU Guang-Shan²

1. College of Life and Environmental Sciences, Minzu University of China, Beijing 100081, China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Received:2010-04-07 Revised:2010-10-26 Online:2011-01-10 Published:2010-12-11
Contact: Hua Li E-mail:lihuamuc@gmail.com
Supported by:
国家“九七三”计划项目(批准号: 2006CB806100)、中央民族大学高等学校111学科创新引智计划项目(批准号: B08044)和中央民族大学985工程项目(批准号: CUN985-03-03)资助.

Abstract

Abstract: A novel metal organo-diphosphonate compound constructed 2D layers with alkaline gas adsorption property has been synthesized through hydrothermal method. The compound is isomorphous and crystallizes in the Monoclinic, C2/c space group. The metal ions are six-coordinate with four oxygen atoms coming from phosphonate and coordinated aqua molecules and two nitrogen atoms coming from 4, 4’-bpy. The two oxygen atoms of phosphonate are uncoordinated which indicated that the structure could absorb some alkaline gas.

Key words: Metal organo-phosphonate, Hydrothermal synthesis, Organic-inorganic hybrid material

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LI Hua*, REN Ha, ZHANG Wei-Wei, QIU Shi-Lun, ZHU Guang-Shan. Synthesis, Structure and Gas Adsorption Property of a Novel 2D Layer Nickel Organo-diphosphonate Compound[J]. Chem. J. Chinese Universities, 2011, 32(1): 28.

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Synthesis, Structure and Gas Adsorption Property of a Novel 2D Layer Nickel Organo-diphosphonate Compound

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