Synthesis and Characterization of Titanium\|containing Styrene Monomer and Polymer

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (1): 196.

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Synthesis and Characterization of Titanium\|containing Styrene Monomer and Polymer

YANG Hong-Ling¹, ZHANG Sheng¹, ZANG Yi-Bo¹, ZHU Fang-Hua², ZHANG Lin², CHEN Xue-Tai^1*

1. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
2. Research Centre of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900, China

Received:2010-02-09 Revised:2010-09-06 Online:2011-01-10 Published:2010-12-11
Contact: Chen Xue-tai E-mail:xtchen@netra.nju.edu.cn
Supported by:
国家自然科学基金委员会-中国工程物理研究院联合基金(批准号: 10676012)资助.

Abstract

Abstract: A styrenic monomer containing dicylopentadienyltitanium group and 2,6-pyridinedicarboxylate has been synthesized and fully characterized. A stable and soluble copolymer was obtained by the solution copolymerization reaction between the titanium-containing monomer and styrene. This copolymer was found to be soluble in THF, CH2Cl2 and toluene and exhibit a glass transition temperature of 106 oC. This titanium-containing polystyrene could be used in the fabrication of the micro-spheres for the ICF experiments.

Key words: Titanium, Styrene, Copolymerization, Synthesis

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YANG Hong-Ling, ZHANG Sheng, ZANG Yi-Bo, ZHU Fang-Hua, ZHANG Lin, CHEN Xue-Tai*. Synthesis and Characterization of Titanium\|containing Styrene Monomer and Polymer[J]. Chem. J. Chinese Universities, 2011, 32(1): 196.

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Synthesis and Characterization of Titanium\|containing Styrene Monomer and Polymer

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