Syntheses, Crystal Structures and Decomposition Kinetics of Complexes of Zinc and Nickel with Amido-Schiff-base as the Ligand

Chem. J. Chinese Universities

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Syntheses, Crystal Structures and Decomposition Kinetics of Complexes of Zinc and Nickel with Amido-Schiff-base as the Ligand

HAN Jing¹, XING Yong-Heng¹*, ZHANG Xing-Jing², ZHOU Guang-Hua², AN Yue², GE Mao-Fa²

1. College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China;
2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Received:2007-01-08 Revised:1900-01-01 Online:2007-08-10 Published:2007-08-10
Contact: XING Yong-Heng

Abstract

Abstract: Two new complexes, (C₉H₇NO₃)Zn(C₃H₄N₂)₂(1) and (C₉H₇NO₃)Ni(C₃H₄N₂)₂(C₄H₅N₂O)•CH₃OH•0.5H₂O(2), with salicylideneglycinyl as the ligands, were synthesized successfully at room temperature in methanol solution, and characterized via elemental analyses, IR spectra, UV-Vis and fluorescence spectra, and X-ray diffraction and thermogravimetric analyses were also carried out.

Key words: Salicylideneglycinyl ligand, Zn complex, Ni complex, Crystal structure, Non-thermal decomposition kinetics

CLC Number:

O614
O641

TrendMD:

HAN Jing¹, XING Yong-Heng¹*, ZHANG Xing-Jing², ZHOU Guang-Hua², AN Yue², GE Mao-Fa². Syntheses, Crystal Structures and Decomposition Kinetics of Complexes of Zinc and Nickel with Amido-Schiff-base as the Ligand[J]. Chem. J. Chinese Universities, doi: .

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Syntheses, Crystal Structures and Decomposition Kinetics of Complexes of Zinc and Nickel with Amido-Schiff-base as the Ligand

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