Synthesis, Characterization and Crystal Structure of Dimer Organotin Complex {[n-Bu2SnO2CCH(CS2NEt2)2]2O}2

Abstract

Abstract: The title complex {[nBu₂SnO₂CCH(CS₂NEt₂)₂]₂O}₂ was synthesized and characterized by elemental analysis, IR, NMR and Xray single crystal diffraction. The results show that the complex belongs to a monoclinic system with space group C₂/c, and unit cell dimensions: a=2.848(5) nm, {b=1.381(2) nm}, c=3.239(6) nm, β=111.11(2)°, Z=4, V=11.884(35) nm³, D-c=1.329 g/cm³, {F(000)}=4 912, S=0.991, R-1=0.053 5, wR₂=0.116 6. The complex has a centrosymmetric dimer structure mode with a fourmembered central endocyclic Sn₂O₂ unit. The endocyclic tin atoms are sixcoordination and have coordition geometry of distorted octahedron. The exocyclic tin atoms are fivecoordination and have coordination geometry of distorted trigonal bipyramid. This complex was tested in vitro against human tumour cell lines, MCF-7 and WiDr, and displayed the higher activity.

Key words: Organotin complex, Bis(N,N-diethyldithiocarbamyl)acetate}, Synthesis, Crystal structure, Biological activity

CLC Number:

TrendMD:

YIN Han-Dong, XUE Sheng-Cai, WANG Qi-Bao. Synthesis, Characterization and Crystal Structure of Dimer Organotin Complex {[n-Bu₂SnO₂CCH(CS₂NEt₂)₂]₂O}₂[J]. Chem. J. Chinese Universities, 2005, 26(4): 631.

[1]	CAO Shujie, LI Hongjun, GUAN Wenli, REN Mengtian, ZHOU Chuanzheng. Progress on the Stereocontrolled Synthesis of Phosphorothioate Oligonucleotides [J]. Chem. J. Chinese Universities, 2022, 43(Album-4): 20220304.
[2]	WANG Ruyue, WEI Hehe, HUANG Kai, WU Hui. Freezing Synthesis for Single Atom Materials [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220428.
[3]	YAO Qing, YU Zhiyong, HUANG Xiaoqing. Progress in Synthesis and Energy-related Electrocatalysis of Single-atom Catalysts [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220323.
[4]	WEI Chunhong, JIANG Qian, WANG Panpan, JIANG Chengfa, LIU Yuefeng. Atomic Scale Investigation of Pt Atoms/clusters Promoted Co-catalyzed Fischer-Tropsch Synthesis [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220074.
[5]	JIN Ruiming, MU Xiaoqing, XU Yan. Bio-chemical Synthesis of Melanin Precursor—— 5，6-Dihydroxyindole（DHI） [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220134.
[6]	ZHANG Xinxin, XU Di, WANG Yanqiu, HONG Xinlin, LIU Guoliang, YANG Hengquan. Effect of Mn Promoter on CuFe-based Catalysts for CO₂ Hydrogenation to Higher Alcohols [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220187.
[7]	ZHOU Zixuan, YANG Haiyan, SUN Yuhan, GAO Peng. Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J]. Chem. J. Chinese Universities, 2022, 43(7): 20220235.
[8]	LU Cong, LI Zhenhua, LIU Jinlu, HUA Jia, LI Guanghua, SHI Zhan, FENG Shouhua. Synthesis， Structure and Fluorescence Detection Properties of a New Lanthanide Metal-Organic Framework Material [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220037.
[9]	LI Yidi, TIAN Xiaochun, LI Junpeng, CHEN Lixiang, ZHAO Feng. Electron Transfer on the Semiconductor-microbe Interface and Its Environmental Application [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220089.
[10]	ZHUANG Jiahao, WANG Dingsheng. Current Advances and Future Challenges of Single-atom Catalysis [J]. Chem. J. Chinese Universities, 2022, 43(5): 20220043.
[11]	FENG Li, SHAO Lanxing, LI Sijun, QUAN Wenxuan, ZHUANG Jinliang. Synthesis of Ultrathin Sm-MOF Nanosheets and Their Visible-light Induced Photodegradation of Mustard Simulant [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210867.
[12]	ZHANG Zhinan, CHENG Haiming, TENG Shiyong, ZHANG Ying. Synthesis and Optical Properties of RbPb₂Cl₅ [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220418.
[13]	XING Peiqi, LU Tong, LI Guanghua, WANG Liyan. Controllable Syntheses of Two Cd（II） Metal-organic Frameworks Possessing Related Structures [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220218.
[14]	TAN Yuling, YANG Ling, YU Hong, NI Chunyan, LANG Jianping. Progress of the Synthesis of High-Nuclearity Ag/S Nanoclusters [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210476.
[15]	WANG Jie, HUO Haiyan, WANG Yang, ZHANG Zhong, LIU Shuxia. General Strategy for In situ Synthesis of NENU-n Series Polyoxometalate-based MOFs on Copper Foil [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210557.

Synthesis, Characterization and Crystal Structure of Dimer Organotin Complex {[n-Bu₂SnO₂CCH(CS₂NEt₂)₂]₂O}₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments