Hydrothermal Synthesis and Characterization of a New Two-dimensional Lanthanum(Ⅲ)-cobalt(Ⅱ) Heterometallic Coordination Polymer La(Hida)Co(ida)2·0.5H2O

Abstract

Abstract: A new lanthanum(Ⅲ)-cobalt(Ⅱ) heterometallic polymeric complex of La(Hida)Co(ida)₂·0.5H₂O(1,ida=iminodiacetate) was hydrothermally synthesized and structurally characterized by the elemental analyses,IR spectrum and the single-crystal X-ray diffraction.The structure of compound 1 consists of one-dimensional lanthanum-cobalt heterometallic chain,which was linked via "linear" tetradentate ida ligands to form the two-dimensional framework.The crystal data for compound 1: monoclinic system,space group(C2/c,) a=0.970 78(19) nm,b=2.412 8(5) nm,c=0.859 64(17) nm,β=114.91(3)°,V=1.826 3(6) nm³,Z=4 and R=0.012 6. Interestingly,the title compound contains ten-coordinate lanthanide(Ⅲ)(ions), which makes it unique as the heteronuclear lanthanide iminoacetate.

Key words: Hydrothermal synthesis, Crystal structure, Heterometallic coordination polymer

CLC Number:

O614

TrendMD:

HE Jiang-Hua, YU Ji-Hong, LI Guang-Hua, BI Ming-Hui, XU Ru-Ren. Hydrothermal Synthesis and Characterization of a New Two-dimensional Lanthanum(Ⅲ)-cobalt(Ⅱ) Heterometallic Coordination Polymer La(Hida)Co(ida)₂·0.5H₂O[J]. Chem. J. Chinese Universities, 2005, 26(11): 1994.

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Hydrothermal Synthesis and Characterization of a New Two-dimensional Lanthanum(Ⅲ)-cobalt(Ⅱ) Heterometallic Coordination Polymer La(Hida)Co(ida)₂·0.5H₂O

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