Chem. J. Chinese Universities ›› 2005, Vol. 26 ›› Issue (10): 1930.

• Articles • Previous Articles     Next Articles

Effects of Silver Films with Different Nano-particle Sizes on SERS of Single-walled Carbon Nanotubes

LIU Bing-Bing1, YU Miao1, LI Dong-Mei1, CUI Tian1, WANG Lin1, YAO Ming-Guang1, YU Shi-Dan1, ZOU Guang-Tian1, WANG Xu2, ZHAO Bing2, SUNDQVIST Bertil3   

  1. 1. National Laboratory of Superhard Materials,
    2. Key Laboratory for Supramolecular Structure and Materials of Ministry of Education,Jilin University,Changchun 130012,China;
    3. Department of Experimental Physics,Umeá University,SE-90187,Umeá,Sweden
  • Received:2004-07-28 Online:2005-10-10 Published:2005-10-10

Abstract: Surface-enhanced Raman Scattering(SERS) spectra of single-walled carbon nanotubes(SWCNTs) on silver films with different nano-particle sizes from 20-100 nm deposited on quartz and glass substrates were studied systematically.The characteristic Raman spectral features of SWCNT G-band and D-band were analyzed.The two bands show a similar tendency with the change of nano-particle size of silver on quartz and glass substrates.The position and the intensity of the G-band are less sensitive to the films silver particle sizes in the studied range,indicating that hexagonal carbon rings are stable and have a weak interaction with silver films.The shape of the D-band is dependent on the silver size.The smaller the silver particle size,the more the contribution of high frequency vibrations to the D-band,indicating that disorder carbon has a strong interaction with the active silver films.

Key words: Single-walled carbon nanotube, Surface-enhanced Raman scattering spectrum, Silver film, Nano-particle size

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