Synthesis,Characterization and Intercalation Behavior of γ-Zirconium Benzylphosphonate-phosphates

Abstract

Abstract: γ-ZrP with a high crystallinity was prepared at 220 ℃. Three γ -zirconium benzylphosphonate-phosphates,formulated as Zr(PO₄)(H₂PO₄)_0.15 (C₆H₅CH₂PO₃H)_0.85 ·0.4H₂O(1, d=1.86 nm), Zr(PO₄) (H₂PO₄)_0.30 (C₆H₅CH₂PO₃H)_0.70 ·0.6H₂O(2, d=1.78 nm) and Zr(PO₄)(H₂PO₄)_0.50 ·(C₆H₅CH₂PO₃H)_0.50 ·0.7H₂O(3, d=1.66 nm),were synthesized and characterized by means of ³¹P MAS NMR,XRD and TG method. The intercalation behavior of the new compounds with α -phenylethylamines are investigated.

Key words: γ-ZrP, Benzylphosphonic acid, γ-Zirconium benzylphosphonate-phosphates, ³¹P MAS NMR, Intercalation

CLC Number:

O614

TrendMD:

HUANG Kun-Lin, YU Ji-Hong, ZOU Yong-Cun, LI Cai-Jin, WANG Guang-Mei, DING Hong, JIN Wei-Jie, XU Ru-Ren . Synthesis,Characterization and Intercalation Behavior of γ-Zirconium Benzylphosphonate-phosphates[J]. Chem. J. Chinese Universities, 2004, 25(8): 1387.

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Synthesis,Characterization and Intercalation Behavior of γ-Zirconium Benzylphosphonate-phosphates

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