Synthesis and Characterization of Novel Bridged Porphyrin Dimers

Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (7): 1204.

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Synthesis and Characterization of Novel Bridged Porphyrin Dimers

FU Shi-Tao, WANG Kai, XIE Zheng, LI Zao-Ying

College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China

Received:2003-08-19 Online:2004-07-24 Published:2004-07-24

Abstract

Abstract: Reaction of 4,4′-dicarboxy-2,2′-bipyridine, 2,6-dibromomethyl pyridine, 2,6-dihydro-xymethyl pyridine and 1,8-diaminonaphthalene with 5-(4-hydroxyphenyl)-10,15,20-triphenyl porphyrin, 5-(4-chloroformacylphenyl)-10,15,20-triphenyl porphyrin and 5-[4-(4′-bromobutoxy)phenyl]-10,15,20-triphenyl porphyrin gave three types bridged diporphyrins 2a-2e, respectively. These intermediates and novel compounds were confirmed by IR, ¹H NMR, MS, UV-Vis and elemental analysis.

Key words: Porphyrin dimers, Synthesis, Structure characterization

CLC Number:

O614

TrendMD:

FU Shi-Tao, WANG Kai, XIE Zheng, LI Zao-Ying . Synthesis and Characterization of Novel Bridged Porphyrin Dimers[J]. Chem. J. Chinese Universities, 2004, 25(7): 1204.

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Synthesis and Characterization of Novel Bridged Porphyrin Dimers

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