Synthesis, Structure and Fluorescence Properties of a Novel Two-dimensional Inorganic-organic Framework Material Zn3(PTC)2(H2O)8·4H2O

Abstract

Abstract: A novel two-dimensional coordination polymer Zn₃(PTC)₂(H₂O)₈·4H₂O was formed by Zn(CH _{3,/sub>COO)₂·2H₂O and 2-pyridine-1,3,5-tricarboxylate(H₃PTC) under the hydrothermal condition at 417 K and characterized by fluorescence. The crystal structure of the compound was determined by single-crystal X-ray diffraction analyses. The six-coordinated Zinc(Ⅱ) center displays an octahedral geometry . The crystal is monoclinic and space group is P2(1)/c with a=0.722 70(14) nm, b= 1.866 7(4) nm , c=1.072 6(3) nm, α=90°, β=103.198(19)°, γ=90°, V=1.408 7(6) nm³, Z=4, D_c= 2.474 Mg/m³, M_r=828.536, μ=3.099 mm^-1 , F(000)=1 060, GOF=0.892, R=0.061 3, wR= 0.133 9 .}

Key words: Inorganic-organic framework material, Pyridinecarboxylic acid, Fluorescence

CLC Number:

O641

TrendMD:

TIAN Ge, LIU Xiu-Jie, FANG Qian-Rong, ZHU Guang-Shan, XIN Ming-Hong, SHI Xin, WU Gang, QIU Shi-Lun . Synthesis, Structure and Fluorescence Properties of a Novel Two-dimensional Inorganic-organic Framework Material Zn₃(PTC)₂(H₂O)₈·4H₂O[J]. Chem. J. Chinese Universities, 2004, 25(4): 784.

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Synthesis, Structure and Fluorescence Properties of a Novel Two-dimensional Inorganic-organic Framework Material Zn₃(PTC)₂(H₂O)₈·4H₂O

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