Preparation of γ-Fe2O3 Nanoparticles by Solid(wet)-phase Grinding

Abstract

Abstract: In this paper, a new method to prepare γ Fe₂O₃ nanoparticles was described. In the presence of polyethylene glycol(PEG 400), the mixture of FeCl₃·6H₂O and NaOH was ground and the γ Fe₂O₃ nanoparticles were prepared. The product obtained was washed and dried at 60 ℃ and calcined at different temperatures for 1 h. XRD, Mssbauer Spectroscopy, TEM, TG DTA and FTIR were used to characterize the samples. The results show that after dried at 60 ℃ for 2 h, the as ground sample was transformed into poor crystalline γ Fe₂O₃ ultrafine powder. After being calcined at 450 ℃ for 1 h, the ultrafine powder became good crystalline γ Fe₂O₃ nanoparticles with particle size of 30 nm. After being calcined at 500 ℃ for 1 h, perfect crystalline γ Fe₂O₃ nanoparticles were gotten with a particle size of 40 nm.

Key words: γ-Fe₂O₃, PEG 400, Nanoparticles, Grinding

CLC Number:

TB383

TrendMD:

JIANG Guo-Hua, JIANG Ji-Sen . Preparation of γ-Fe₂O₃ Nanoparticles by Solid(wet)-phase Grinding[J]. Chem. J. Chinese Universities, 2004, 25(3): 405.

References

[1] Takahash i N.,Kakuda N.,Ueno A.et al..Jpn.J.App .lPhys.[J],Part 2,1989,28(2);L 244—L 247 [2] Chhabra V.,Ayyub P.,Chattopadhyay S.et al..Mater.Lett.[J],1996,26(1—2);21—26 [3] Suresh K.,Patil K.C..J.Mater.Sc.iLett.[J],1993,12(80);572—574 [4] Zio lo R.F.,Giannelis E.P.,Wein sten B.A.et al..Science[J],1992,257(5 067);219—223 [5] Kang Y.S.,Risbud S.,Rabo lt J.F.et al..Chem.Mater.[J],1996,8(9);2 209—2 211 [6] Schw ertm ann U.,Co rnell R.M..Iron Ox ides in the Labo rato ry2p reparation and Characterization[M],Weinheim;Wiley-V CH Ver2lag Gm bH,2000;141—142 [7] Rahm an M.M.,Verkataram an A..J.Therm.Ana.lCalo rim etry[J],2002,68(1);91—101 [8] Kim J.S.,Kim I.B.,Kang H.C.et al..Yoop Hakhoech i[J],1992,29(12);942—948 [9] Chen D.R.,Xu R.R..J.So ld State Chem.[J],1998,137(20);185—190 [10] Vein tem llas-Verdaguer S.,Mo ralesM.P.,Serna C..J.Mater.Lett.[J],1998,35(3—4);227—231 [11] Randrianan toandro N.,Mercier A.M.,Hervieu M.et al..Mater.Lett.[J],2001,47(3);150—158 [12] JIANG Ji-Sen(姜继森),GAO Lian(高　濂),YAN G Xie-Long(杨燮龙).Acta of Physico-Chimica(物理化学学报)[J],2000,16 (4);312—316 [13] Ed.by M A Ru-Zhang(马如璋),WU Bing(吴　兵),LI Yu-Pu(李玉璞)et al..The Handbook of Mossbauer Spectrum(穆斯堡尔谱学手册)[M],Beijing;Press ofMetallurgical Industry,1993;369 [14] Wu X.,Wang D..J.Co llo id In terface Sc.i[J],2000,222(1);37—40 [15] Ed.by Ligh t IndustrialDesign ing In stitute(轻工业设计院).The Handbook of Physical and Chem icalData fo r Dom estic Chem ical In-dustry(日用化工理化数据手册)[M],Beijing;Ligh t Industrial Press,1988;839 [16] Mano ravi P.,Jo seph M.,Sivakum ar N..J.Phys.Chem.So lids[J],1998,59(8);1 271—1 277 [17] Cheng Sh ih-Kai,Wang Cheng-Ch ien,Chen Chuh-Yang.Mater.Chem.Phys.[J],2003,78(3);581—590 [18] Ed.by WU Jin-Guang(吴瑾光),XU Zhen-Hua(许振华),L I Qiong-Yao(李琼瑶)et al..Technology and App lication of ModernTim es FT IR(近代傅立叶变换红外光谱技术及应用),Volum e[M],Beijing;Press of Scien tific and Technological Literature,1994;136 [19] QIU Chun-Xi(邱春喜),JIANG Ji-Sen(姜继森),ZHAO Zhen-Jie(赵振杰)et al..Journal of Inorgan ic Materials(无机材料学报) [J],2001,16(50);957—960

Preparation of γ-Fe₂O₃ Nanoparticles by Solid(wet)-phase Grinding

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