Hydrothermal Synthesis and Structure Characterization of C4H8N2H4·Zn(HPO3)2

Abstract

Abstract: A new zinc hydrogen phosphite C₄H₈N₂H₄·Zn(HPO₃)₂ was prepared by hydrothermal method in the presence of piperazine as a structure-directing agent and the crystal structure was determined by single-crystal X-ray diffraction analysis and further characterized by X-ray powder diffraction, IR, ICP, elemental analysis and TG analysis. This compound has one-dimensional anionic chains containing four-membered rings built from corner-sharing linked alternating ZnO₄ tetrahedra and HPO₃ pseudo pyramids. The zinc hydrogen phosphite chains are interacted with the templates of diprotonated piperazine by N—H…O hydrogen bond. Crystal data for C₄H₈N₂H₄·Zn(HPO₃)₂;monoclinic, space group C2/c. a=1.774 8(2) nm, b=0.724 28(9) nm, c=0.880 87(11) nm, β= 105.345(3)°, V=1.091 9(2) nm³, Z=4, D_c=1.907 Mg/m³, R₁=0.022 9, wR₂=0.058 8.

Key words: Hydrothermal synthesis, Crystal structure, Piperazine, Zinc-phosphite, Pseudo tetrahedron

CLC Number:

O614

TrendMD:

SHI Su-Hua, LI Guang-Hua, XIN Ming-Hong, LI Yue-Ming, DING Hong, XU Jia-Ning, ZHU Guang-Shan, SONG Tian-You, QIU Shi-Lun . Hydrothermal Synthesis and Structure Characterization of C₄H₈N₂H₄·Zn(HPO₃)₂[J]. Chem. J. Chinese Universities, 2004, 25(2): 230.

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Hydrothermal Synthesis and Structure Characterization of C₄H₈N₂H₄·Zn(HPO₃)₂

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