Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (12): 2322.

• Articles • Previous Articles     Next Articles

Enhanced Photo-luminescence Effect of Nano-CdS in the Nano-CdS/PANI Composite Films by PANI

XI Yan-Yan1, ZHOU Jian-Zhang1, ZHANG Yan1, DONG Ping1, CAI Cheng-Dong1, HUANG Huai-Guo2,3, LIN Zhong-Hua1   

  1. 1. State Key Laboratory for Physical Chemistry of the Solid Surface, Department of Chemistry, Institute of Physical Chemistry, Xiamen University, Xiamen 361005, China;
    2. Xiamen Zijin Science and Technology Co., LTD. Xiamen 361000, China;
    3. Fujian Zijin Research Institute of Mining and Metallurgy, Fujian Zijin Mining Industry Co., LTD., Longyan 364200, China
  • Received:2003-10-09 Online:2004-12-24 Published:2004-12-24

Abstract: CdS/PANI(poly-aniline) composite film was prepared by the current impulse electrodeposition on the PANI/PATP(p-aminothiophenol)/Au. The structure and performances were characterized by means of SEM and UV-Vis, IR, Raman, fluorescence and XPS spectroscopies. The CdS nano-particles in the nano-CdS/PANI composite films show the size quantization effect and the enhanced photoluminescence effect by PANI. The photo-generated carriers transfer mechanism from PANI into nano-CdS was proposed to explain the effect. The chemical interaction between NH-groups of PANI chains and S 2- ions of nano-CdS is found.

Key words: Nano-CdS, PANI, Composite film, Photo-luminescence

CLC Number: 

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