Chem. J. Chinese Universities ›› 2004, Vol. 25 ›› Issue (10): 1972.

• Articles • Previous Articles     Next Articles

Synthesis and Characterization of a New Chiral PAEK Containing 1,1′-Bi-2-naphthyl Moiety

CAO Hui1, BEN Teng1, WANG Xing1, LIU Na1, LIU Xin-Cai1, ZHAO Xiao-Gang1, ZHANG Wan-Jin1, WEI Yen2   

  1. 1. Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China;
    2. Department of Chemistry, Drexel University, PA 19104, USA
  • Received:2003-11-27 Online:2004-10-24 Published:2004-10-24

Abstract: A new chiral poly(aryl ether ketone)(PAEK) containing 1,1′-bi-2-naphthyl moiety was synthesized. The chiral PAEK was characterized by IR, 1H NMR, GPC and DSC. The chiral behavior of the chiral PAEK was investigated by vibrational circular dichroism(VCD) preliminaryly, and we found it possesses the chiral feature. It would be attempted to be chiral stationary phase to realize chiral separation.

Key words: Binaphthyl moiety, Poly(aryl ether ketone), Chiral stationary phase

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