A New and Easy Post Functionalization Approach to Synthesize Polymers Containing Indole-based Chromophore Side Groups

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (9): 1700.

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A New and Easy Post Functionalization Approach to Synthesize Polymers Containing Indole-based Chromophore Side Groups

LI Zhen¹, QIN Jin-Gui¹, LI Shao-Jun², YE Cheng²

1. College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China;
2. Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China

Received:2002-08-08 Online:2003-09-24 Published:2003-09-24

Abstract

Abstract: A new synthetic strategy was developed to prepare polymers with indole-based chromophore side chains. Thus, polymers 1 that contain indole groups as side chains was obtained by a direct reaction. And then a post azo coupling of p-nitrobenzenediazonium fluoroborate toward the indole ring in polymers 1 afforded indole-based chromophore-functionalized polymers 2. The polymers were well characterized and exhibited an excellent solubility in common organic solvents. The poled film of polymers 2 reveals a resonant d₃₃value of 25 pm/V obtained by second harmonic generation (SHG) measurements.

Key words: Post functionalization, Synthesis, Indole, Second harmonic generation

CLC Number:

O634.4

TrendMD:

LI Zhen, QIN Jin-Gui, LI Shao-Jun, YE Cheng. A New and Easy Post Functionalization Approach to Synthesize Polymers Containing Indole-based Chromophore Side Groups[J]. Chem. J. Chinese Universities, 2003, 24(9): 1700.

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A New and Easy Post Functionalization Approach to Synthesize Polymers Containing Indole-based Chromophore Side Groups

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