Synthesis and Characterization of a Novel 1-D Hybrid Zinc Phosphate (2,2′-bipy)2Zn2(PO4H)(PO4H2)2

Chem. J. Chinese Universities ›› 2003, Vol. 24 ›› Issue (6): 989.

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Synthesis and Characterization of a Novel 1-D Hybrid Zinc Phosphate (2,2′-bipy)₂Zn₂(PO₄H)(PO₄H₂)₂

YAO You-Wei^1,2, YANG Guo-Yu ¹

1. State Key Laboratory of the Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2. Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130023, China

Received:2002-01-17 Online:2003-06-24 Published:2003-06-24

Abstract

Abstract: Trying to transgraft the idea of adjusting polyoxometallates′ micro-structures by rationally designing structure building units composed of ligand and "secondary metal" to the synthesis of open-framework zinc phosphate results in a novel 1-D hybrid zinc phosphate, (2,2′-bipy)²Zn²(PO₄H)·(PO₄H₂)²(FJ-10: Fujian Institute of Research on the Structure of Matter). X-ray single crystal analysis reveals FJ-10 belongs to a triclinic crystal system, space group P-1, a=1.038 18(6) nm, b= 1.230 41(7) nm, c=1.234 81(7) nm, α=97.207 0(10)°, β=109.411 0(10)°, γ=113.081 0(10)°, V=1.307 79(13) nm³, R¹=0.039 9, _wR₂=0.101 3. The topology structure of FJ-10′s framework is characterized by PO³(OH) bridged 4-rings. FJ-10 exemplifies firstly the π-π stacking of hybrid chains whose structure-building units are involved in ZnO³N². FJ-10 predicts the novel hybrid transition phosphates.

Key words: Hydrothermal synthesis, Zinc phosphate, Crystal structure

CLC Number:

O614

TrendMD:

YAO You-Wei, YANG Guo-Yu  . Synthesis and Characterization of a Novel 1-D Hybrid Zinc Phosphate (2,2′-bipy)₂Zn₂(PO₄H)(PO₄H₂)₂[J]. Chem. J. Chinese Universities, 2003, 24(6): 989.

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Synthesis and Characterization of a Novel 1-D Hybrid Zinc Phosphate (2,2′-bipy)₂Zn₂(PO₄H)(PO₄H₂)₂

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