Studies of the Surface Activity of Gleditsin and the Thermodynamic Properties of Its Binary Mixtures

Abstract

Abstract: The surface activity and the thermodynamic properties of gleditsin saponin(GS)(C₂₉ H₄₆(OH)COOH) were studied by surface tension method at 0, 15, 25, 35, 45 and 60 ℃. With the method, the surface activity of its binary aqueous solutions with C₁₂ H₂₅-SO₃Na(AS), C₁₂ H₂₅ (OC₂H₄)₃-SO₄Na(AES), C₇F₁₅ CO₂Na(OBS), C₁₆ H₃₃ NMe₃ Br(CTAB), C₈H₁₇-Ph(EO)₁₀ OH(Triton) and C₁₂ H₂₅ (EO)₉OH(AEO₉) were also studied at 25 ℃. The composition of the surface adsorption layers, molecular interaction parameters and the molecule exchanging energy of surfactants of these mixtures were calculated according to the dimensional crystal model and the regular solution theory with the help of the curves γ～lg c. The relationship between activity and molecule exchanging energy of surfactants were emphatically discussed. The results show that gleditsin saponin mainly acts as a nonionic surfactant in aqueous solution but as a weak acid anionic surfactant when mixed with cationic CTAB. The synergism order of its binary mixtures is: GScationic>GSnonionic>GSanionic.

Key words: Gleditsin, Surfactant, Surface tension, Dimensional crystal model, Molecular interaction parameter, Molecule exchanging energy

CLC Number:

O642.1

TrendMD:

WANG Zheng-Wu, LI Gan-Zuo, MU Jian-Hai, GUAN Da-Ren, LIAO Li-Ling, LOU An-Jin. Studies of the Surface Activity of Gleditsin and the Thermodynamic Properties of Its Binary Mixtures[J]. Chem. J. Chinese Universities, 2002, 23(8): 1583.

[1]	QIAO Zhenghua, FAN Qi, HAO Jingcheng. Silicone Surfactant-enhanced Dual Networks and High Temperature Resistance Porous Silicone Elastomers [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220384.
[2]	HAN Yixiu, WU Dianguo, LI Hongpu, YIN Hongyao, MEI Yongjun, FENG Yujun, ZHONG Zuqin. Interactions Between Hydrophobic Associating Poly（sodium acrylate） and a Zwitterionic Surfactant in Non-aqueous Media and Low Temperature Environment [J]. Chem. J. Chinese Universities, 2021, 42(6): 2056.
[3]	HU Xueyi, HAN Lulu, FANG Yun, XIA Yongmei. Admicelles and Adsolubilization of Extended Surfactants on Alumina [J]. Chem. J. Chinese Universities, 2021, 42(3): 843.
[4]	ZHENG Zirui, LI Zilu, ZHAO Kefei, WU Tianyue, ZHANG Chenhui, GAO Yuxia, DU Fengpei. Interfacial Behaviors of Bio-based Surfactant Escin [J]. Chem. J. Chinese Universities, 2021, 42(10): 3107.
[5]	ZHANG Xuan,ZHANG Tianci,JIANG Ping,GE Jijiang,ZHANG Guicai. Enhancement of CO₂ Foam Stability with Modified Silica Nanoparticles in High Salinity Brine ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1076.
[6]	JI Lei,GUO Fanzuo,WANG Kehan,WANG Lei. Surfactant-assisted Formation of Nanoporous Pt Particles as Co-catalyst Loaded on P25 and Enhanced Photocatalytic Performance^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1501.
[7]	YANG Yihan,WANG Dong,ZHANG Zhang,XU Yan. Activation of Esterification Activity of Rhizopus Chinensis Lipase in Organic Media by Surfactant^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1948.
[8]	YANG Jiarui, WANG Yifu, WANG Jilin, WANG Lulu, FENG Ruijiang. In situ Initiation, Polymerization and Construction of Cationic Active Sites of Gemini Molecules in Polysulfone Substrates^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1829.
[9]	DONG Shigang, GAO Yingbo, GUAN Zichao, WANG Haipeng, WANG Xia, DU Ronggui, SONG Guangling. Inhibition Effect of Polyvinylpyrrolidone on Corrosion of Reinforcing Steel in Simulated Concrete Pore Solutions^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1260.
[10]	LONG Shijun,CHEN Mingmin,ZHAO Youjiao,WANG Xiaotao,LI Xuefeng,LIAO Yonggui. Regulation of Gemini Surfactant on Photochromic Behavior of PVA Dispersed Spiropyran Organogel Thin Film^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 1078.
[11]	YIN Jinchao, CHEN Yukai, JIANG Jianzhong, CUI Zhenggang. Synthesis and Properties of pH and Redox Dual-switchable Surfactant^† [J]. Chem. J. Chinese Universities, 2017, 38(9): 1645.
[12]	XU Hongmei, LI Jie, QIAO Yunfan, ZHANG Min, ZHANG Hongyang, WANG Yuerong, HU Ping. Dispersion of Single-wall Carbon Nanotubes in Bile Salt Surfactants and Separation of SWCNTs(6,5) by Aqueous Two-phase Extraction^† [J]. Chem. J. Chinese Universities, 2017, 38(7): 1148.
[13]	LI Dan, WU Qian, LIU Li, SUN Xiaori, GUO Meng, FENG Yimin. Preparation and Stability of Gemini Surfactant Modified Gold Nanofluids^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1829.
[14]	WANG Yifu, DONG Jinxin, WANG Jilin, WANG Lulu, FENG Ruijiang. Ordered Self-assembly of Gemini Molecules in Mesoporous Silica Channels Constructing Normal Micelles to Assist the Migration of OH-† [J]. Chem. J. Chinese Universities, 2017, 38(1): 141.
[15]	GUO Haiquan, MA Xiaoye, JIN Rizhe, KANG Chuanqing, QIU Xuepeng, GAO Lianxun. Preparation and Properties of Nanocomposites Based on Polyimide and Polyfluorinated Surfactant-pillared Layered Double Hydroxide^† [J]. Chem. J. Chinese Universities, 2016, 37(2): 403.

Studies of the Surface Activity of Gleditsin and the Thermodynamic Properties of Its Binary Mixtures

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments