Luminescence Behavior on the Formation Complex of Water Soluble Calixarene Derivative with Earth Terbium(Ⅲ) Ion

Abstract

Abstract: The luminescent behavior on formation 1:1 complex of 25, 26, 27, 28 tetra carboxylic acid 5, 11, 17, 23 calixarenesulfonate(L₂) and terbium(Ⅲ) ion was investigated by means of fluorescence spectra. The results showed that the pHvalue of the solution had obviousan influence on the fluorescence intensity of L₂·Tb³⁺ complex, but the fluorescence intensity was hardly changed over the pHrange from 6 to 11. The complex exhibits a higher emission quantum yield (φ =0.31) in aqueous solution, which indicates energy transfer type emission. The complexation behavior of L₂ with trivalent lanthanoid ions(Tb³⁺ and Eu³⁺) was also studied in aqueous boracic acid(hydrochloric acid buffer solution(pH_8.0) at 25 ℃ by UV-Vis and fluorescence measurements. The spectrophotometric titrations have been performed to give the complex stability constants (K_S) for the stoichiometric 1:1 inclusion complexation of L₂ with Tb³⁺ and Eu³⁺. The complex stability for L₂·Eu³⁺ was higher than that for L₂·Tb³⁺, but no characteristic fluorescence was found.

Key words: Water soluble calixarene, Terbium complex, Energy transfer, Fluorescence property

CLC Number:

O641
O614

TrendMD:

ZHANG Ning, ZHAO Bang-Tun, LIU Yu. Luminescence Behavior on the Formation Complex of Water Soluble Calixarene Derivative with Earth Terbium(Ⅲ) Ion[J]. Chem. J. Chinese Universities, 2002, 23(8): 1533.

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Luminescence Behavior on the Formation Complex of Water Soluble Calixarene Derivative with Earth Terbium(Ⅲ) Ion

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