Synthesis, Characterization and Spectrum Property of a New Red-Fluorescence Porphine

Abstract

Abstract: A new polyarylaminophenylporphine, tetra(p-N,N-diphenylamino)phenylporphine(TDPAPPH₂) was synthesized by direct condensation of pyrrole and p-N, N-diphenylaminophenyl alde-hyde.Its molecular structure was characterized by elemental analysis, ¹H NMR, IRand UV-Vis spectra.Compared with trtraphenylporphine (TPPH₂) and tetra (p-`amino) phenylporphine (TAPPH₂), the absorption and emission peaks of TDPAPPH₂ had large red-shifts due to the changes of LUMO and HOMO levels.

Key words: Tetra-(p-N,N-diphenyl) aminophenylporphine, Synthesis, UV-Vis Spectrum, OLED

CLC Number:

O621.3

TrendMD:

QUO Can-Cheng, YIN Zhen-Ming, ZHU Jin-Tao, NI Rong. Synthesis, Characterization and Spectrum Property of a New Red-Fluorescence Porphine[J]. Chem. J. Chinese Universities, 2002, 23(5): 832.

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Synthesis, Characterization and Spectrum Property of a New Red-Fluorescence Porphine

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