Study on the Synthesis and Catalysis Application on Phase Transfer Reaction of Quaternary Ammonium Cyclodextrin Resins

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (S1): 278.

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Study on the Synthesis and Catalysis Application on Phase Transfer Reaction of Quaternary Ammonium Cyclodextrin Resins

WANG Yong-Jian¹, ZHANG Zheng-pu², HE Bing-Lin²

1. Department of Biochemical Engineering, Tianjin University, Tianjin 300072;
2. Institute of Polymer Chemistry, Nankai University, Tianjin 300071, China

Received:2001-08-27 Online:2001-12-31 Published:2001-12-31
Contact: zhangzp@nankai.edu.cn E-mail:zhangzp@nankai.edu.cn

Abstract

Abstract:

Cyclodextrin resin with quaternary ammonium salt group was synthesized by activation cyclodextrin polymer with epichlorohydrm under alkali condition. The influences of experimental conditions, concentration of NaOH, reaction temperature, reaction time and other conditions, on activating results were studied in detail. The results show that the preparation method is very easy and various kinds of quaternary anrmonium cyclodextrin resins can be synthesized by this method. These resins can notably catalyzed the reaction of benzyl chloride with KSCN to produce benzyl thiocyanate.

Key words: Cyclodextrin resin, Phase transfer catalyst, Activation, Quaternary ammonium salt, Benzyl thiocyanate, Synthesis

CLC Number:

O63.2

TrendMD:

WANG Yong-Jian, ZHANG Zheng-pu, HE Bing-Lin. Study on the Synthesis and Catalysis Application on Phase Transfer Reaction of Quaternary Ammonium Cyclodextrin Resins[J]. Chem. J. Chinese Universities, 2001, 22(S1): 278.

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Study on the Synthesis and Catalysis Application on Phase Transfer Reaction of Quaternary Ammonium Cyclodextrin Resins

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