Study on the Ternary System:Cu(Ⅱ)-8-Hydroxyquinoline Functionalized Tetraamine Macrocycle-α-Amino Acid

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (S1): 172.

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Study on the Ternary System:Cu(Ⅱ)-8-Hydroxyquinoline Functionalized Tetraamine Macrocycle-α-Amino Acid

SU Xun-Cheng, LIN Hua-Kuan, ZHU Shou-Rong, LIU Tian-Fu, LENG Xue-Bing, CHEN Rong-Ti

Department of Chemistry, Nankai University, Tianjin 300071, China

Received:2001-07-04 Online:2001-12-31 Published:2001-12-31
Contact: linhk@public.ipt.tj.cn E-mail:linhk@public.ipt.tj.cn

Abstract

Abstract:

Two 8-hydroxyquinoline substituted dioxotetraamine macrocycles, L₁ and L₂, have been synthesized and their association constants with metal complexes in aqueous solution have been studied. At 25.0 ±0.1℃,I=0.1mol·dm^-3 NaNO₃,the stability constants of the ternary system: Cu(Ⅱ)-L(L₁ or L₂)-α-amino acid were investigated and the appropriate structures with respect to the titration species were proposed according to the literature and the obtained data.. The results show that good linear-free-energy relationship exist in the ternary systems.

Key words: dioxotetraamine macrocycle, functionalization, stability, linear relationship

CLC Number:

O642.4

TrendMD:

SU Xun-Cheng, LIN Hua-Kuan, ZHU Shou-Rong, LIU Tian-Fu, LENG Xue-Bing, CHEN Rong-Ti. Study on the Ternary System:Cu(Ⅱ)-8-Hydroxyquinoline Functionalized Tetraamine Macrocycle-α-Amino Acid[J]. Chem. J. Chinese Universities, 2001, 22(S1): 172.

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Study on the Ternary System:Cu(Ⅱ)-8-Hydroxyquinoline Functionalized Tetraamine Macrocycle-α-Amino Acid

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