Synthesis and Characterization of a Novel Hybrid Single Crystal [Ga3(PO4)3F2]H3O·(H3NCH2CH2)2NH2

Abstract

Abstract: Anovel three dimensional fluorinated gallium-phosphate has been hydrothermally synthesized by using diethylenetriamine as an organic structure directing agent. X-ray single crystal structure analysis indicates this compound crystallizes in the orthorhombic space group Pbca, a=1.6056(7) nm, b=10114 (4) nm, c=1.8546(5) nm, V=3.0116(19) nm³, Z=4. The three dimensional framework based on linkage of corner sharing polyhedron PO₄, GaO₄Fand GaO₄F 2 delimit ten ring channels along b axis in which the triply protonated amines are located serving as charge compensating guests and supporters.

Key words: Gallium-phosphate, Hydrothermal synthesis, Diethylenetriamine

CLC Number:

O641

TrendMD:

YAO You-Wei, ZHAO Yong-Nan, YUE Shan-Tang, XU Heng-Lian, LIANG Hong-Bin, ZHAO Da-Qing . Synthesis and Characterization of a Novel Hybrid Single Crystal [Ga₃(PO₄)₃F₂]H₃O·(H₃NCH₂CH₂)₂NH₂[J]. Chem. J. Chinese Universities, 2001, 22(9): 1450.

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Synthesis and Characterization of a Novel Hybrid Single Crystal [Ga₃(PO₄)₃F₂]H₃O·(H₃NCH₂CH₂)₂NH₂

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