Synthesis and Characterization of Terpolymer of Methyl Methacrylate, Styrene and Dibutyltin Maleate

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (2): 325.

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Synthesis and Characterization of Terpolymer of Methyl Methacrylate, Styrene and Dibutyltin Maleate

YAN Zhi-Sen¹, QIAN Qing-Rong², CHEN Qing-Hua², ZHANG Wen-Gong³

1. Editorial Department of Journal;
2. Experimental Center;
3. Institute of Polymer Science, Fujian Normal University, Fuzhou 350007, P.R.China

Received:2000-03-22 Online:2001-02-24 Published:2001-02-24

Abstract

Abstract: Benzoic peroxide(BPO) was used as an initiator in bulk terpolymerization of dibutyltin maleate(DBTM), methyl methacrylate(MMA) and styrene(St). The conditions of copolymerization were discussed. The copolymer was characterized by GPC, IR, ¹H NMRand TGanalysis; and the results showed the occurrence of copolymerization. The number-average molecular weight of terpolymer was above 10⁴. The dynamic thermorheological test showed that, the thermal stability of copolymer was superior to that of DBTM. It may be used as polyfunctional PVCstabilizer.

Key words: Terpolymer, Synthesis, Characterization, PVC thermal stabilizer

CLC Number:

O634

TrendMD:

YAN Zhi-Sen, QIAN Qing-Rong, CHEN Qing-Hua, ZHANG Wen-Gong . Synthesis and Characterization of Terpolymer of Methyl Methacrylate, Styrene and Dibutyltin Maleate[J]. Chem. J. Chinese Universities, 2001, 22(2): 325.

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Synthesis and Characterization of Terpolymer of Methyl Methacrylate, Styrene and Dibutyltin Maleate

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