Synthesis and Crystal Structure of A Novel One-dimensional Cyano-bridged Chain Complex [Eu(DMF)4·(H2O)2Mn(CN)6·H2O] n

Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (2): 167.

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Synthesis and Crystal Structure of A Novel One-dimensional Cyano-bridged Chain Complex [Eu(DMF)₄·(H₂O)₂Mn(CN)₆·H₂O] _n

YAN Bing^1,2, WANG Shi Xi^1,3, CHEN Zhi Da^1,2

1. State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
2. Peking University The University of Hong Kong Joint Laboratory of Rare Earth Materials and Bioinorganic Chemistry, Beijing 100871, China;
3. Department of Chemistry, Jining Teachers College, Jining 272125, China

Received:2000-01-28 Online:2001-02-24 Published:2001-02-24

Abstract

Abstract: Using K₃Mn(CN)₆, N,N-dimethylformamide(DMF) and Eu(NO₃)₃·6H₂Oas reactants, a novel one dimensional cyano bridged chain complex [Eu(DMF)₄·(H₂O)₂Mn(CN)₆·H₂O]_n has been first synthesized and characterized with elemental analysis, IR, UVspectra and X-ray crystal analysis. The complex crystallizes in the monoclinic P2_1/c space group, with lattice parameters a =1.2992(3) nm, b =1.2764(3) nm, c =1.9154(4) nm, β =109.42(3)°, V =2.9956(12) nm³, D_x=1.573 Mg/m³, Z =4, R =0.0372, R_w=0.0962, GOF=1.095. The complex shows one dimensional chain structure due to the two bridging CNbetween Eu and Mn atom.

Key words: Synthesis, Crystal structure, One dimensional chain, Cyano-bridged complex

CLC Number:

O614

TrendMD:

YAN Bing, WANG Shi Xi, CHEN Zhi Da. Synthesis and Crystal Structure of A Novel One-dimensional Cyano-bridged Chain Complex [Eu(DMF)₄·(H₂O)₂Mn(CN)₆·H₂O] _n[J]. Chem. J. Chinese Universities, 2001, 22(2): 167.

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Synthesis and Crystal Structure of A Novel One-dimensional Cyano-bridged Chain Complex [Eu(DMF)₄·(H₂O)₂Mn(CN)₆·H₂O] _n

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