Synthesis of Novel Inorganic Nanoclusters Between Keggin-type Cation [AlO4Al12(OH)24(H2O)12]7+ and Heteropolyoxometalates

Abstract

Abstract: The novel class of inorganic nanoclusters, [AlO₄Al₁₂(OH)₂4(H₂O)₁₂][SiW₁₁₀₃₉CoCl]·1¹H₂O, [AlO₄Al₁₂(OH)₂4(H₂O)₁₂][P₂W₁₈₀₆₂]Cl₅₃₃H_2Oand [AlO₄Al₁₂(OH)₂4(H₂O)₁₂]₂[NaP₅W_30O₁₁₀]·24H₂O, consisting of Keggin cations and heteropolyoxometalates, has been synthesized and characterized by ICP, IRand NMR. It is proved that the intrinsic identities of Keggin cation and heteropolyanions of the clusters are preserved within the gels.

Key words: Keggintype cation, Heteropolyoxometalates, Synthesis, Structural characterization, Gel

CLC Number:

O614

TrendMD:

PENG Ge, HU Chang-Wen, CHEN Li-Dong, WANG En-Bo . Synthesis of Novel Inorganic Nanoclusters Between Keggin-type Cation [AlO₄Al₁₂(OH)₂₄(H₂O)₁₂]^⁷⁺ and Heteropolyoxometalates[J]. Chem. J. Chinese Universities, 2001, 22(10): 1629.

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Synthesis of Novel Inorganic Nanoclusters Between Keggin-type Cation [AlO₄Al₁₂(OH)₂₄(H₂O)₁₂]^⁷⁺ and Heteropolyoxometalates

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