Chem. J. Chinese Universities ›› 2001, Vol. 22 ›› Issue (1): 70.

• Articles • Previous Articles     Next Articles

First Enantioselective Syntheses of (2R,3R)- and (2S,3S)-3-(4-Hydroxy-3- methoxyphenyl)-2-hydroxymethyl-1,4-benzodioxan-6-carbaldehyde

GU Wen-Xin, WU Tong-Xing, CHEN Xiao-Chuan, PAN Xin-Fu   

  1. College of Chemistry and Chemical Industry, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
  • Received:2000-06-14 Online:2001-01-24 Published:2001-01-24

Abstract: An enantioselective and regioselective total synthesis approach to chiral 1,4-benzodioxane lignans(2R,3R)- and (2S,3S)-2-(4-hydroxy-3-methoxyphenyl)-3-hydroxymethyl-1,4-benzodioxan-6-carbaldehyde was reported firstly.

Key words: Benzodioxane, Lignans, Enantioselectivity, Asymmetry, Synthesis

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