Synthesis and Characterization for(η2-C60 )[Fe(CO)2(C5H5)]2

Abstract

Abstract: The first binuclear iron fullerene derivative of(η²-C₆₀ )[Fe(CO)₂(C₅H₅)]₂ , which was yellow brown and sensitive to air and moisture, was prepared by the reaction of trans-[Fe(CO)₂(C₅H₅)]₂ with C₆₀ in benzene under an atmosphere of dried nitrogen using conventional Schlenk techniques and has been characterized by using elementary analysis and IR, ¹H NMR, ¹³C NMRand XPSspectra. The infrared spectrum of the title compound indicates the disappearance of ν_CO at 1760 cm^-1 for bridge carbonyl and the appearance of the only terminal COlying at a higher wave number than that of the starting material, which reveals the electron-deficient behavior of C₆₀ . And the important ¹H, ¹³C NMRchemical shift and XPSof trans-[Fe(CO)₂(C₅H₅)]₂ , C₆₀ and its novel complex along with their relative assignments are briefly discussed.

Key words: C₆₀, Binuclear iron complex, C₆₀-metal complex, Synthesis

CLC Number:

O613.71

TrendMD:

LIU Xiang, GAO Yi-Ci, SU Zhong-Xing, WANG Yao-Yu, SHI Qi-Zhen . Synthesis and Characterization for(η²-C₆₀ )[Fe(CO)₂(C₅H₅)]₂[J]. Chem. J. Chinese Universities, 2000, 21(8): 1174.

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Synthesis and Characterization for(η²-C₆₀ )[Fe(CO)₂(C₅H₅)]₂

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