Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (6): 829.

• Articles •     Next Articles

Synthesis and Structure of Bis(2,4-dimethylpentadienyl)gadolinium Chloride

WANG Jian-Hui1, MU Ying1, SHI Zhan2, ZHANG Suo-Bo1, FENG Shou-Hua2   

  1. 1. Department of Chemistry;
    2. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China
  • Received:1999-05-06 Online:2000-06-24 Published:2000-06-24

Abstract: Anew complex {〔2,4-(CH3)2C5H52GDcl}2 was obtained by the reaction of [2,4-(CH3)2C5H5]3Gd with GDcl3 in toluene at refluxing temperature. The compound {[2,4-(CH3)2C5H5]2GDcl}2 crystallizes in the monoclinic system, space group P21/ n with a =0.89141(18) nm, b =1.4486(3) nm, c =1.15925(15) nm, β = 92.996(18)°, V =1.4949(4) nm3 , Z =3.

Key words: Lanthanide complexes, Bis(pentadienyl)gadolinium chloride, Synthesis, Crystal structure

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