Studies on the Diffusion-controlled Solid-solid State Reaction by Means of XRD

Chem. J. Chinese Universities ›› 1999, Vol. 20 ›› Issue (3): 361.

• Articles • Previous Articles Next Articles

Studies on the Diffusion-controlled Solid-solid State Reaction by Means of XRD

ZHOU Yi-Ming, YE Xiang-Rong, LI Dao-Hua, XIN Xin-Quan

Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093

Received:1998-03-17 Online:1999-03-24 Published:1999-03-24

Abstract

Abstract: Solid-solid state condensation reaction of p-hydroxybezaldehyde and p-chloroaniline was conducted at low-heating temperature. The reaction product was proved to be the corresponding Schiff base. TG-DTA and XRD measurements were performed to investigate the solid-solid state reaction process. It is fairly definite that the reaction is diffusion-controlled.

Key words: Solid-solid state condensation reaction, Diffusion-controlled, XRD patterns, Schiff base

CLC Number:

O721

TrendMD:

ZHOU Yi-Ming, YE Xiang-Rong, LI Dao-Hua, XIN Xin-Quan . Studies on the Diffusion-controlled Solid-solid State Reaction by Means of XRD[J]. Chem. J. Chinese Universities, 1999, 20(3): 361.

[1]	XU Dandan, ZOU Xiucheng, LUO Jing, LIU Ren. Synthesis and Characterization of Phenothiazine-based Schiff Bases as Visible Light Photoinitiators [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210857.
[2]	CAO Cheng,CAO Tian,YAN Penji,WANG Qingyun,YUE Guoren,JI Xiangdong. High Selectivity of Enol-keto Tautomers Imine Derivative for the Recognition of Co²⁺^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1544.
[3]	XIONG Xingquan, JIANG Yunbing, XIAO Shangyun, SHI Lin, SONG Sida. Highly Efficient Synthesis of 1,2,3-Triazoles Catalyzed by Schiff Base Functionalized Chitosan-CuBr Catalyst^† [J]. Chem. J. Chinese Universities, 2016, 37(10): 1863.
[4]	WANG Zijian, SUN Xiaohong, LIU Yuanfa, CHEN Bang, SHEN Shengqiang, JIN Ruyi, MA Haixia. Synthesis and Biological Activities of 1,2,4-Triazole Schiff Bases Containing Pyrazole Rings^† [J]. Chem. J. Chinese Universities, 2015, 36(7): 1315.
[5]	HUANG Jian, LIU Zhigang, FAN Ruiqing, DONG Yuwei, ZHANG Huijie, WANG Yulei, YANG Yulin. Synthesis, Characterization and Blue-emission of Cd(Ⅱ)Coordination Polymers with μ-Chlorine-Bridging One-dimensional Chain Structures^† [J]. Chem. J. Chinese Universities, 2015, 36(3): 411.
[6]	QU Zhi, LI Xiang, PANG Xuan, DUAN Ranlong, GAO Bo, CHEN Xuesi. Aluminum Schiff Base Catalyst for Ring-opening Polymerization of ε-Caprolactone^† [J]. Chem. J. Chinese Universities, 2014, 35(4): 869.
[7]	ZHANG Shu-Yuan, JIANG Ping-Ping, LENG Yan, XU Yu-Cheng, MO Guan-Tian, BIAN Gang. Synthesis of cis-Dioxomolybdenum(Ⅵ)-tridentate Schiff Base Complexes and Its Catalytic Activity on the Epoxidation of Soybean Oil [J]. Chem. J. Chinese Universities, 2013, 34(7): 1703.
[8]	QIU Zhao-Lai, LI Wen-Hong, ZHU Hai-Fei, LIU Qian, LI Yuan. Synthesis, Crystal Structure and Antifungal Activities of 3-(CH₂)_nCO₂C₂H₅-1,5-Benzothiazepines [J]. Chem. J. Chinese Universities, 2013, 34(3): 579.
[9]	YIN De-Fei, CHENG Hong-Bo, HUO Xiao-Lian, LI Hai-Ning, PANG Mei-Li*. Synthesis and Properties of Novel Photochromic Dyads Based on Spiropyrans and Schiff Base [J]. Chem. J. Chinese Universities, 2011, 32(10): 2301.
[10]	LI Xiao-Juan, SUN Shi-Ling, LIU Yan, ZHAO Hai-Bo, LIU Chun-Guang, QIU Yong-Qing*. DFT Studies on Electronic Spectra and Second\\|order Nonlinear Optical Properties of Schiff Base Ligands Containing Ferrocene and Their Ni(Ⅱ) Complexes [J]. Chem. J. Chinese Universities, 2011, 32(1): 155.
[11]	YANG Su-Hua, PANG Mei-Li*, GUO Xin-Fu, LI Jing-Jing, HAN Jie, MENG Ji-Ben. Synthesis and Properties of Novel Photochromic Dyads Based on Spirooxazine and Schiff Base [J]. Chem. J. Chinese Universities, 2010, 31(5): 976.
[12]	LI Huan-Min, GAO Nan, LIU Lei, SHEN Si-Le, LUO Gui-Min*. Novel Trifunctional Salicylaldehyde Schiff Base Derivative with GPX, SOD and CAT Activities [J]. Chem. J. Chinese Universities, 2009, 30(7): 1353.
[13]	ZHANG Ping, LIU Na, WANG Lan-Zhi, LI Yuan^*. Synthesis of 3-(3S-t-Butoxyl)succinimidyl-β-lactams and the Stereoselectivity of the Reaction [J]. Chem. J. Chinese Universities, 2009, 30(1): 90.
[14]	LUO Guo-Tian*, ZHENG Sheng-Wei, XU Qing-Bing. Synthesis, Optical and Thermal Properties of Novel Schiff Base Complexes Containing Porphyrin Copper(Ⅱ) and Zinc(Ⅱ) [J]. Chem. J. Chinese Universities, 2008, 29(7): 1307.
[15]	WANG Chang-Rong¹, LÜ Jian², GAO Lu¹, WANG Yong-Mei², ZHANG Jin-Hong^1*. Plasmid DNA Cleavage by Valine-Schiff Base-Cu Complexes [J]. Chem. J. Chinese Universities, 2008, 29(11): 2201.

Studies on the Diffusion-controlled Solid-solid State Reaction by Means of XRD

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments