Preparation and Evaluation of 8-Quinolinol Derivatized β-Cyclodextrin Bonded Silica for High-performance Liquid Chromatography

Abstract

Abstract: 8-Quinolinol derivatized β-cyclodextrin bonded silica(QCDS) has been prepared for high-performance liquid chromatography. The resulting bonded silica was characterized by using elemental analysis, thermal analysis and solid state NMR. The separation performance of QCDS for positional isomers, dansylamino acids, phenylpropionic acids and nucleosides was investigated. It was found that the retention of p-nitroaniline and p-nitrophenol was much smaller on the QCDS than on β-cyclodextrin bonded silica(CDS), whereas the retention of their ortho-and meta-isomers was similar on the both bonded stationary phases.

Key words: HPLC, Bonded silica stationary phase, β-Cyclodextrin, 8-Quinolinol

CLC Number:

O652.63

TrendMD:

FENG Yu-Qi, XIE Min-Jie, DA Shi-Lu . Preparation and Evaluation of 8-Quinolinol Derivatized β-Cyclodextrin Bonded Silica for High-performance Liquid Chromatography[J]. Chem. J. Chinese Universities, 1999, 20(11): 1708.

[1]	PAN Mengyun, FENG Liuxing, LI Hongmei. Absolute Quantification of Haemoglobin in Whole Blood by Species-unspecific Isotope-dilution Liquid Chromatography-inductively Coupled Plasma Mass Spectrometry [J]. Chem. J. Chinese Universities, 2020, 41(9): 1983.
[2]	WANG Tianqi,YU Qiongwei,FENG Yuqi. Analysis of Imidazole Propionic Acid in Serum of Patients with Type 2 Diabetes Based on NiO@SiO₂ Solid-phase Extraction Coupled with Liquid Chromatography-Mass Spectrometry ^† [J]. Chem. J. Chinese Universities, 2020, 41(2): 262.
[3]	ZHAO Mengxin, MENG Zhe, LI Heping, MA Zongqin, ZHAN Haijuan, LIU Wanyi. Photodegradation of Antibiotic in Environmental Water by Graphene Oxide Modulation Bismuth Molybdate Under Visible Light Irradiation [J]. Chem. J. Chinese Universities, 2020, 41(11): 2479.
[4]	ZHAO Huanxi,WANG Qiuying,SUN Xiuli,LI Xue,MIAO Rui,WU Dongxue,LIU Shuying,XIU Yang. Discrimination of Ginseng Origins and Identification of Ginsenoside Markers Based on HPLC-MS Combined with Multivariate Statistical Analysis^† [J]. Chem. J. Chinese Universities, 2019, 40(2): 246.
[5]	MIAO Rui,WU Dongxue,WANG Qiuying,ZHAO Huanxi,LI Xue,XIU Yang,LIU Shuying. Rapid Separation of Ginsenosides Based on Multi-walled Carbon Nanotubes^† [J]. Chem. J. Chinese Universities, 2018, 39(10): 2178.
[6]	LI Nan, ZHAO Huanxi, LI Jing, WANG Nan, YU Bohao, YUE Hao, YU Shanshan. Transformation of Total Notoginsenosides by Recombinant Endocellulase Fpendo5A^† [J]. Chem. J. Chinese Universities, 2017, 38(12): 2185.
[7]	LI Xue, ZHAO Huanxi, MIAO Rui, LI Wenying, XIU Yang, LIU Shuying. Structure and Pathway Research on Chemical Transformation of Ginsenoside Rb₁ via HPLC-HRMS/MSⁿ/QqQ Technique^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1730.
[8]	PI Zifeng, WANG Qianqian, ZHANG Jing, Song Fengrui, LIU Zhiqiang. Effect of Schisandra Fruit on Neurochemicals in Hippocampus of Diabetic Encephalopathy Rat Using Online MD-HPLC-MS/MS^† [J]. Chem. J. Chinese Universities, 2015, 36(3): 442.
[9]	ZHANG Yongpo, ZHANG Yang, SUN Huailin. Stereo Selective Synthesis and Absolute Configuration Determination of (2E,4S)-4-(t-butoxycarbonylamino)-5-[(3S)-2'-oxo-3'-pyrrolidinyl]-2-pentenoic Acid Ethyl Ester^† [J]. Chem. J. Chinese Universities, 2014, 35(2): 292.
[10]	YAO Hua, JIN Yongri, YANG Jie, LI Lanjie, SUN Ting, SHI Xiaolei, LI Xuwen. Conversion Rule of Rare Ginsenosides Produced from Major Ginsenosides by Confined Microiwave Promoted Degradation Method^† [J]. Chem. J. Chinese Universities, 2014, 35(11): 2317.
[11]	LI Lai-Sheng, CHEN Hong, MA Hai-Ping, FANG Yi-Shan. Preparation, Characterization and Evaluation of Magnolol-bonded Silica Gel Stationary Phase for Reversed-phase Liquid Chromatography [J]. Chem. J. Chinese Universities, 2012, 33(04): 707.
[12]	CAO Li-Yan, WANG Hai-Xia, SHI Juan, ZHOU Ye-Hong, LIU Wen-Juan, ZHANG Guo-Mei, SHUANG Shao-Min*. Synthesis and Characterization of Sulfobutylether-β-cyclodextrin/Fe3O4 Hybrid Magnetic Nano-composite [J]. Chem. J. Chinese Universities, 2011, 32(9): 2152.
[13]	ZHANG Wang, CHEN Ming, DIAO Guo-Wang*. Preparation of β-Cyclodextrin Functionalized Polyacrylonitrile Nanofibers and Its Adsorption for Methylene Blue [J]. Chem. J. Chinese Universities, 2011, 32(9): 2227.
[14]	XU Zhi-Feng*, KUANG Dai-Zhi, WEN Ge, ZHANG Fu-Xing, WANG Jian-Qiu, LI Jun-Hua. Preparation and Binding Properties in Aqueous Media of Cholic Acid Imprinted Polymers [J]. Chem. J. Chinese Universities, 2011, 32(8): 1727.
[15]	WANG Qi, CHENG Xian, HE Rui, WANG Dong-Ni, LU Chang-Sheng*, MENG Qing-Jin. Different Assemblies of Monotonous Maleonitriledithiolate\\|modified β-Cyclodextrins in Solution [J]. Chem. J. Chinese Universities, 2011, 32(3): 700.

Preparation and Evaluation of 8-Quinolinol Derivatized β-Cyclodextrin Bonded Silica for High-performance Liquid Chromatography

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments