Phase Diagram, Structure and Fluorescence Spectra of CsxRb1-xYbI3System

Abstract

Abstract: The Cs_xRb_1-xYbI₃system in the composition 0≤ x ≤1 was synthesized and the phase diagram of Cs_xRb_1-xYbI₃was measured by the different thermal analyses(DTA). This phase diagram was completed and certified by the X-ray powder diffraction and flourescent spectra. This system is a limited solid solution with peritectic reaction and eutectoid reaction. The temperature of peritectic point and eutectoid point are 627 ℃ and 371 ℃ respectively. There are three kinds of solid solution in the system: a RbYbI 3 type solid solution and a high temperature phase of RbYbI₃type solid solution when 0≤ x ≤0.5 and a CsYbI₃type solid solution when0.75≤ x ≤1.0.

Key words: Reduced rare earth iodides, One-step synthesis method, Phase diagram, Solid solution

CLC Number:

O642

TrendMD:

XU Min, WANG Shi-Hua, WANG Mei-Tian, LIU Chun-Sheng. Phase Diagram, Structure and Fluorescence Spectra of Cs_xRb_1-xYbI₃System[J]. Chem. J. Chinese Universities, 1998, 19(8): 1296.

[1]	WU Zhuoyan, LI Zhi, ZHAO Xudong, WANG Qian, CHEN Shunpeng, CHANG Xinghua, LIU Zhiliang. A Highly Efficient One-step Preparation Method of Nano-silicon and Carbon Composite for High-performance Lithium Ion Batteries [J]. Chem. J. Chinese Universities, 2021, 42(8): 2500.
[2]	WANG Xingfan, ZHOU Huan, ZHOU Kuo, JIN Fenli, YANG Junfang. Comprehensive Thermodynamic Model and Polythermal Phase Diagram Prediction of Nitrate Type Brine Systems [J]. Chem. J. Chinese Universities, 2021, 42(10): 3175.
[3]	PENG Shaoqin, LI Ziqin, HUANG Mingtao, LI Yuexiang. Preparation of Zn₂In₂S₅ Photocatalyst by Post-treatment with Hydrochloric Acid for Effective Photocatalytic Hydrogen Evolution^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1677.
[4]	CHEN Ying, ZHAO Yu, LI Jing, HAN Xingyue. One-step Synthesis of Hydrangea-like BiOCl/Br Solid Solution Photocatalyst with Co-template Method^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 2045.
[5]	LIU Shujing, LI Jiangtao, GU Fang, WANG Haijun. Phase Structure of A_a Type of Patchy Colloids^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1888.
[6]	LIU Xuewu,CHEN Shuhua,ZHAN Shiping. Experimental Study and Theoretical Phase Diagram Calculation for Polystyrene Membranes Prepared by Supercritical CO₂-induced Phase Inversion^† [J]. Chem. J. Chinese Universities, 2016, 37(8): 1573.
[7]	MA Yong, LI Xiangzhi, LI Yongtao, LIU Dongming, ZHANG Qing’an, SI Tingzhi. Phase Structures and Hydrogen Storage Properties of Mg₂Ni_1-_xCo_x Alloys Prepared by Solid Solution Sintering^† [J]. Chem. J. Chinese Universities, 2016, 37(10): 1776.
[8]	LI Zhaowan, QIAO Zhanping, CHEN Xin, DANG Yuanlin, YANG Qichao. Equilibria for the CsBr-TmBr₃-H₂O and CsBr-TmBr₃-HBr(~13%)-H₂O Systems at 298.15 K and Thermodynamic and Fluorescent Properties of New Solid-phase Compound [J]. Chem. J. Chinese Universities, 2015, 36(9): 1759.
[9]	KONG Lingzhi, WANG Qian, XU Li, YAN Yongsheng, LI Huaming, YANG Xiangguang. Influence of CuO on Ce-Zr-O₂ Dispersion on Catalytic Properties in CO Oxidation^† [J]. Chem. J. Chinese Universities, 2015, 36(7): 1372.
[10]	HU Biao, ZHOU Peng, PAN Chengling, DU Yong, LIU Shuhong, LI Yiwei, HAN Jiangjun. Theoretical Study on the Binary Phase Diagrams of the Zr-X (X=Li, Na, K, Sc, Hf) Systems^† [J]. Chem. J. Chinese Universities, 2015, 36(10): 1939.
[11]	YIN Huiqin, WANG Kun, LIU Wenguan, XIE Leidong, HAN Han, WANG Wenfeng. Thermodynamic Modeling of the LiF-CrF₃ Binary System^† [J]. Chem. J. Chinese Universities, 2014, 35(12): 2668.
[12]	ZHU Yan, YAO Wei-Qin, CHEN Shao-Jie, TIAN Long-Zhao, YUAN Shuai. Phase Diagram and Temperature Influence of SDS/n-pentanol-cyclohexane-water Pseudo Ternary Systems [J]. Chem. J. Chinese Universities, 2013, 34(5): 1254.
[13]	JIA Jin-Qian, XIE Xue-Jia, LIANG Zhen-Hai, ZHANG Xiao-Chao, FAN Cai-Mei, HAN Pei-De. First-principles Study of Ti-doped SnO₂ Semiconductor Solid Solutions [J]. Chem. J. Chinese Universities, 2012, 33(05): 1050.
[14]	ZHANG Zhi-Wei, DING Wei, LI Zhong, DONG Zhi-Long, YU Tao, QU Guang-Miao, WANG Hui-Min, LUO Shi-Qiong. Properties of Microemulsion Formed by Different Alkyl Aryl Sulfonates [J]. Chem. J. Chinese Universities, 2012, 33(02): 395.
[15]	HUANG Xue-Li*, WANG Xue-Feng, CHEN Li-Juan. Liquid-Solid Equilibrium of Na⁺, K⁺, Mg²⁺//Cl^-, SO^2-₄, NO^-₃, H₂O System at 25 ℃ [J]. Chem. J. Chinese Universities, 2011, 32(6): 1378.

Phase Diagram, Structure and Fluorescence Spectra of Cs_xRb_1-xYbI₃System

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments