Qualitative and Quantitative Analysis of Two-way Chromatographic/Spectroscopic Data with Overlapping Peaks(Ⅱ) Annihilation of Rank and Resolution by Projection and Determination of Polycyclic Aromatic Hydrocarbons in Air-borne Particulate

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (8): 1227.

• Articles • Previous Articles Next Articles

Qualitative and Quantitative Analysis of Two-way Chromatographic/Spectroscopic Data with Overlapping Peaks(Ⅱ) Annihilation of Rank and Resolution by Projection and Determination of Polycyclic Aromatic Hydrocarbons in Air-borne Particulate

CHEN Di-Zhao, LIANG Yi-Zeng, SHEN Hai-Lin, CUI Hui, YU Ru-Qin

College of Chemistry and Chemical Engineering, Institute of Chemometrics and Chemical Sensing Technology, Hunan University, Changsha, 410082

Received:1997-07-07 Online:1998-08-24 Published:1998-08-24

Abstract

Abstract: A new chemometric approach, annihilation of rank and resolution by projection(ARRP) has been developed in this paper. The chromatographic peaks can be directly qualified and quantified without resolution of the other chromatographic peaks. The approach has been successfully applied to the qualitative and quantitative analysis of complex real multicomponent system with PAHs phenanthrene, anthracene, fluoranthene and pyrene as desired components in air-borne paritculate.

Key words: Chemometrics, Annihilation of rank and resolution by projection, Two-way chromatography, Polycyclic aromatic hydrocarbons, Qualitative and quantitative analysis

CLC Number:

O657.7

TrendMD:

CHEN Di-Zhao, LIANG Yi-Zeng, SHEN Hai-Lin, CUI Hui, YU Ru-Qin. Qualitative and Quantitative Analysis of Two-way Chromatographic/Spectroscopic Data with Overlapping Peaks(Ⅱ) Annihilation of Rank and Resolution by Projection and Determination of Polycyclic Aromatic Hydrocarbons in Air-borne Particulate[J]. Chem. J. Chinese Universities, 1998, 19(8): 1227.

[1]	DENG Hongri, CAO Xiaomei, WANG Jingbo, LI Xiangyuan. Rate Rules for Hydrogen Abstraction Reactions of Polycyclic Aromatic Hydrocarbons and Unsaturated Radicals [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210563.
[2]	ZHANG Na, WAN Xin, SONG Xuyan, HUANG Long, ZHENG Jingjing, XING Jun. Application of Octadecyl Ionic Liquid Hybrid Solid-phase Microextraction Monolithic Column in the Detection of Polycyclic Aromatic Hydrocarbons in Coffee^† [J]. Chem. J. Chinese Universities, 2017, 38(6): 1033.
[3]	WANG Cuicui, YU Xiaoming, CAI Wensheng, SHAO Xueguang. Determination of Serum Urea by Near-infrared Diffuse Reflectance Spectroscopy Using Silver Mirror for Enhancing the Detectability^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 1947.
[4]	FAN Shu-Xian, HUANG Hong-Li, GU Kai-Hua, LI Hong-Shuang, ZHU Bin, ZHANG Hong-Liang, FAN Yang. Effect of Fog Process on the Size Distribution of Polycyclic Aromatic Hydrocarbons in the Atmospheric Aerosol PM₁₀ [J]. Chem. J. Chinese Universities, 2010, 31(12): 2375.
[5]	JIANG Jun-Duo, WU Hai-Long*, XIA A-Lin, ZHU Shao-Hua, LIU Di-Si, ZHANG Hui-Feng, YU Ru-Qin. Determination of Honokiol and Magnolol in Both Human Plasma and Complex Magnoliae Officinalis by Second-order Calibration Coupled to Three-dimensional Excitation-emission Fluorescence Spectra [J]. Chem. J. Chinese Universities, 2008, 29(1): 71.
[6]	XI Chun-Yu, LI Guo-Dong, ZHAO Xu, TIAN Ye, ZHANG Yu, CHEN Jie-Sheng. Synthesis and Characterization of Polycyclic Aromatic Hydrocarbons in GaPO₄-LTA Single Crystals [J]. Chem. J. Chinese Universities, 2004, 25(9): 1617.
[7]	LEI Lian-Di, ZHANG Hong-Rui, YANG De-Suo, WU Long-Min . Reaction of Hydroxy-substituted Polycyclic Aromatic Hydrocarbons with Nitric Oxide [J]. Chem. J. Chinese Universities, 2004, 25(10): 1863.
[8]	QI Yun-Peng, WU Yu-Tian, LI Tong-Hua, CHAI Yi-Feng, WANG Bin, ZHANG Guo-Qing . Application of Heuristic Evolving Latent Projection(HELP) in the Resolution of Tailing Coeluting Chromatograms [J]. Chem. J. Chinese Universities, 2003, 24(2): 241.
[9]	QI Yu-Hua, XU Lu . Correlation Analysis of the Structures and pK_a Values of Carboxylic Acids [J]. Chem. J. Chinese Universities, 2002, 23(8): 1489.
[10]	TAN Yong-Xi, JIANG Jian-Hui, XIE Hong-Ping, LIANG Yi-Zeng, YU Ru-Qin . Estimation of Rank by Chemical Subspace Invariant to Linear Transformation Method [J]. Chem. J. Chinese Universities, 2001, 22(8): 1319.
[11]	ZHENG Yu-Ying, JIANG Lin-Qin, ZHAO Jian-Xi, XU Xiu-Zhi . Solubilization of Polycyclic Aromatic Hydrocarbons in F127 and P123 Aqueous Micellar Solutions [J]. Chem. J. Chinese Universities, 2001, 22(4): 617.
[12]	ZHENG Jian-Bin, ZHANG Hong-Quan, GAO Hong . Oscillographic Chronopotentiometry with Fourier Self-deconvolution [J]. Chem. J. Chinese Universities, 2000, 21(7): 1037.
[13]	WANG Ya-Yun, LI Tong-Hua, CONG Pei-Sheng, ZHU Zhong-Liang . The Analysis of Electrolysis Process of the Aniline Using Chemometrics Method [J]. Chem. J. Chinese Universities, 2000, 21(10): 1484.
[14]	DING Jie, XIE Su-Yuan, YU La-Jia, HUANG Rong-Bin, ZHENG Lan-Sun . null [J]. Chem. J. Chinese Universities, 1999, 20(12): 1936.
[15]	GAO Zhi, HE Xi-Wen, LI Yi-Jun, ZHAO Jie . Theoretical Study on Composite Sampling and Monte Carlo Simulation [J]. Chem. J. Chinese Universities, 1999, 20(12): 1853.

Qualitative and Quantitative Analysis of Two-way Chromatographic/Spectroscopic Data with Overlapping Peaks(Ⅱ) Annihilation of Rank and Resolution by Projection and Determination of Polycyclic Aromatic Hydrocarbons in Air-borne Particulate

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments