Synthesis and Sulfonation of Layered Zirconium Phosphate Phenylphosphonate

Abstract

Abstract: The main factors in the synthesis of layered zirconium phosphate phenylphosphonate Zr(PO₄H)_2-n(PO₃Ph)_nwere investigated. At F^-/Zr⁴⁺=12 and H₃PO₄/Zr⁴⁺=20, a series of homogeneous Zr(PO₄H)_2-n(PO₃Ph)_n(n=0～2) were synthesized by changing the amount of phenylphosphonic acid. The crystals are thermally stable below 400 ℃. The phenyl groups in the layered structure can be sulfonated almost quantitatively. The sulfonated products Zr(PO₄H)_2-n(PO₃PhSO₃H)_nhave abundant acidic sites and they are also stable below 300 ℃.

Key words: Zirconium phosphate phenylphosphonate, Synthesis, Thermostability, Sulfonation

CLC Number:

O643.1

TrendMD:

XIAO Jin-Bing, XU Jin-Suo, TANG Yi, GAO Zi . Synthesis and Sulfonation of Layered Zirconium Phosphate Phenylphosphonate[J]. Chem. J. Chinese Universities, 1998, 19(7): 1107.

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Synthesis and Sulfonation of Layered Zirconium Phosphate Phenylphosphonate

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