Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (7): 1011.

• Articles •     Next Articles

Synthesis of Fullerene Ethylenediamine Derivative Platinum Complex and Its Catalytic Behavior in the Hydrosilylation of Olefins

CHEN Yuan-Yin1, FANG Peng-Fei1, ZHU Ling2, SHENG Rong-Sheng2   

  1. 1. School of Chemistry, Wuhan University, Wuhan, 430072;
    2. Department of Analysis and Measurement, Wuhan University, Wuhan, 430072
  • Received:1997-07-28 Online:1998-07-24 Published:1998-07-24

Abstract: Fullerene derivative ethylenediamine platinum complex was prepared by reacting fullerene(C60) with ethylenediamine, potassium chloroplatinite sequentially. The complex exhibited high catalytic activities for the hydrosilylation of olefins with triethoxysilane, and nearly 100% regioselectivity for styrene α-adduct.

Key words: Fullerene, Platinum complex, Hydrosilylation catalyst, Regioselectivity

CLC Number: 

TrendMD: