The Studies of Synthesis and Spectral Characterization of Bis[N,N'-ethylene-2,2'-(phenylmethylene) bis(3,4-dimethylpyrrole-5-aldimino)]dimanganese and Biomimetic Catalytic Reaction

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (3): 385.

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The Studies of Synthesis and Spectral Characterization of Bis[N,N'-ethylene-2,2'-(phenylmethylene) bis(3,4-dimethylpyrrole-5-aldimino)]dimanganese and Biomimetic Catalytic Reaction

CHEN Xin-Bin, ZHU Shen-Jie, GUI Ming-De

Department of Chemistry, Nankai University, Tianjin, 300071

Received:1997-04-15 Online:1998-03-24 Published:1998-03-24

Abstract

Abstract: This paper first reports the synthesis and spectral characterization of bis [N,N'-ethylene 2,2'-(phenylmethylene)bis(3,4-dimethylpyrrole-5-aldimino)] dimanganese as well as the biomimetic catalytic properties for the monooxygenation of cyclohexane with PhIO. The results show that the catalytic properties and stability of this binuclear manganese complex are similar to those of TPPMnCl and better than those of other Schiff base complexes known.

Key words: Schiff base, Synthesis, Mimicking cytochrome, Monooxidation

CLC Number:

O627.7

TrendMD:

CHEN Xin-Bin, ZHU Shen-Jie, GUI Ming-De. The Studies of Synthesis and Spectral Characterization of Bis[N,N'-ethylene-2,2'-(phenylmethylene) bis(3,4-dimethylpyrrole-5-aldimino)]dimanganese and Biomimetic Catalytic Reaction[J]. Chem. J. Chinese Universities, 1998, 19(3): 385.

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The Studies of Synthesis and Spectral Characterization of Bis[N,N'-ethylene-2,2'-(phenylmethylene) bis(3,4-dimethylpyrrole-5-aldimino)]dimanganese and Biomimetic Catalytic Reaction

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