A Research for the Catalysis Kinetics Analysis with Chemical Relaxation Method

Abstract

Abstract: A chemical relaxation kinetics analysis(CRKA) method has been proposed for the first time. The basic theory has been proved systematically and was applied to determine trace copper. Stopped-flow equipment was used for analyzing the system of Fe(Ⅲ)-S₂O₃^2- catalyzed by Cu(Ⅱ). We studied the influence of pH value, medium and reagent on relaxation parameter (1/τ) and obtained the linear relation of 1/τ and concentration. The analytical results of synthetic samples show that the CRKA method has an obvious advantage.

Key words: Chemical relaxation, Catalysis kinetics analysis, Copper

CLC Number:

O652

TrendMD:

HUANG Zheng-Hua, LIN Zhi-Xin, CAI Ru-Xiu, ZHANG Ke. A Research for the Catalysis Kinetics Analysis with Chemical Relaxation Method[J]. Chem. J. Chinese Universities, 1998, 19(2): 219.

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A Research for the Catalysis Kinetics Analysis with Chemical Relaxation Method

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