Synthesis,Structure and Magnetism of [Nd(ONO2)6][Cu(Im)(phen)2]2(OH)·4H2O

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (2): 179.

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Synthesis,Structure and Magnetism of [Nd(ONO₂)₆][Cu(Im)(phen)₂]₂(OH)·4H₂O

NIU Shu-Yun¹, YANG Zhong-Zhi¹, YANG Qing-Chuan², YANG Bing³, CAO Jin-Quan³, YANG Guang-Di³

1. Chem. Dept., Liaoning Normal Univ., Dalian, 116029;
2. Chem. Dept, Peking Univ., Beijing, 100871;
3. Department of Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun, 130023

Received:1996-12-24 Online:1998-02-24 Published:1998-02-24

Abstract

Abstract: The crystal of [Nd(ONO₂)₆][Cu(Im)(phen)₂]₂(OH)·4H₂O was synthesized and its structure of its single crystal was determined by X-ray diffraction. The crystal is triclinic system, space group P1 with a = 1.0126(2) nm, b = 1.1792(2) nm, c = 1.3985 nm, α=111.32(3)°, β=93.17(3)°, γ=90.33(3), V = 1.5526(5) nm³, Z=1, D_c=1.700 g/cm³, F (000) =801, R =0.043, R_w=0.070. UV-Vis-NIR, IR and magnetic susceptibility were determined and the related properties of the complex were discussed. It is found that the title complex possesses the behavior of anti-ferromagnetic material at low-temperature.

Key words: Synthesis, Crystal structure, Molecular magnet, Anti-ferromagnetic behaviour

CLC Number:

O614

TrendMD:

NIU Shu-Yun, YANG Zhong-Zhi, YANG Qing-Chuan, YANG Bing, CAO Jin-Quan, YANG Guang-Di. Synthesis,Structure and Magnetism of [Nd(ONO₂)₆][Cu(Im)(phen)₂]₂(OH)·4H₂O[J]. Chem. J. Chinese Universities, 1998, 19(2): 179.

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Synthesis,Structure and Magnetism of [Nd(ONO₂)₆][Cu(Im)(phen)₂]₂(OH)·4H₂O

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