Synthesis and Crystal Structure of the Charge Transfer Complex [N-(2-Tosylamidoethyl)-aza-12-crown-4]·IHCCl3

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (12): 2009.

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Synthesis and Crystal Structure of the Charge Transfer Complex [N-(2-Tosylamidoethyl)-aza-12-crown-4]·IHCCl₃

WAN Jia-Yi, LIU Jie, QIN Sheng-Ying

Department of Chemistry, Sichuan Union University, Chengdu, 610064

Received:1997-12-16 Online:1998-12-24 Published:1998-12-24

Abstract

Abstract: The title complex A· IHCCl₃ A=CH₃C₆H₄SO₂NHC₂H₄(NC₈H₁₆ O₃) has been prepared and characterized by X-ray diffraction, IRand ¹HNMR. The C-H…Ihydrogen bond length equals 0.389 nm. It crystallizes in monoclinic system and space group P2₁/n with unit cell paramers: a =0.7364(7) nm, b =1.6732(0) nm, c =2.1413(6) nm, β =99.09(1)°, Z =4, V =2.6055(5) nm³ and R₁=0.0479, R₂=0.0424.

Key words: Lariat crown ether, Solvation, Charge transfer, Crystal structure, Synthesis

CLC Number:

O621.29

TrendMD:

WAN Jia-Yi, LIU Jie, QIN Sheng-Ying . Synthesis and Crystal Structure of the Charge Transfer Complex [N-(2-Tosylamidoethyl)-aza-12-crown-4]·IHCCl₃[J]. Chem. J. Chinese Universities, 1998, 19(12): 2009.

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Synthesis and Crystal Structure of the Charge Transfer Complex [N-(2-Tosylamidoethyl)-aza-12-crown-4]·IHCCl₃

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