Studies on the Product of Ion-molecule Reaction of Halogeno-benzene in Gas Phase by MS/MS

Chem. J. Chinese Universities ›› 1998, Vol. 19 ›› Issue (1): 107.

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Studies on the Product of Ion-molecule Reaction of Halogeno-benzene in Gas Phase by MS/MS

LI Zhi-Li, LIU Shu-Ying, XU Wen-Guo, GUO Xing-Hua

Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022

Received:1996-11-28 Online:1998-01-24 Published:1998-01-24

Abstract

Abstract: The fragmentations of the product ions produced by the ion-molecule reaction of the halogeno-benzene (chlorobenzene, bromobenzene and iodobenzene) were studied using the collision-induced dissociation. The main product ions of the ion-molecule reaction of three kinds of halogeno-beneze include the dimeric ions, m/z(2M-X) ions and m/z(2M-2X) ions. The CID spectra of these ions were compared with that of the protonated bromodiphenyl and biphenyl. The formation mechanism and the structure of the product ions were obtained.

Key words: Chlorobeneze, Bromobenzene, Iodobenzene, Ion-molecule reaction, Mass spectrometry/mass spectrometry

CLC Number:

O657.6

TrendMD:

LI Zhi-Li, LIU Shu-Ying, XU Wen-Guo, GUO Xing-Hua . Studies on the Product of Ion-molecule Reaction of Halogeno-benzene in Gas Phase by MS/MS[J]. Chem. J. Chinese Universities, 1998, 19(1): 107.

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Studies on the Product of Ion-molecule Reaction of Halogeno-benzene in Gas Phase by MS/MS

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